Synthesis, crystal structure and properties of [Er(C6H5NO2)3(H2O)2]n(1.5nZnCl4)·(2nH2O) with strong luminescence

Four three‐dimensional heterometallic coordination polymers, [Ln2Cu4I3(IN)7(H2O)]n (1, 2) and [LnCu3.5I3(IN)3.5(H2O)3]n·nH2O (3, 4) [HIN = isonicotinic acid, Ln = Nd (1), Gd (2), La (3), Eu (4)] were hydrothermally synthesized by using lanthanide oxides, isonicotinic acid, copper chloride, and potassium iodide. The different molar ratio of raw materials results in two distinct types of three‐dimensional frameworks of compounds 1–4. The structure of compounds 1 and 2 are constructed by the layer modules of [Ln2(IN)7(H2O)]nn– and Cu4I3 clusters, whereas that of compounds 3 and 4 are built by dimeric Ln2(IN)6(H2O)6 and layered polymeric [Cu7I6]nn+ units.

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Syntheses and Crystal Structures of Ln^III–Cu^I Coordination Polymers

Zhang

Chen

2010

Zeitschrift anorg allge chemie

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Monomer, chain, layer and 3-D framework constructed by linear 4′-(4-carboxyphenyl)-2,2′:6′,2″-terpyridine

Yang

Chen

et al. 2018

Inorganica Chimica Acta

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RETRACTED: Treatment activity of a new luminescent thermostable Sm(III) complex on preeclampsia

Sun

Zhou

Chi

et al. 2022

Inorganica Chimica Acta

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Synthesis, crystal structure and properties of [Er(C6H5NO2)3(H2O)2]n(1.5nZnCl4)·(2nH2O) with strong luminescence

Cited by 9 publications

References 23 publications

Syntheses and Crystal Structures of Ln^III–Cu^I Coordination Polymers

Syntheses and Crystal Structures of Ln^III–Cu^I Coordination Polymers

Monomer, chain, layer and 3-D framework constructed by linear 4′-(4-carboxyphenyl)-2,2′:6′,2″-terpyridine

RETRACTED: Treatment activity of a new luminescent thermostable Sm(III) complex on preeclampsia

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Synthesis, crystal structure and properties of [Er(C6H5NO2)3(H2O)2]n(1.5nZnCl4)·(2nH2O) with strong luminescence

Cited by 9 publications

References 23 publications

Syntheses and Crystal Structures of LnIII–CuI Coordination Polymers

Syntheses and Crystal Structures of LnIII–CuI Coordination Polymers

Monomer, chain, layer and 3-D framework constructed by linear 4′-(4-carboxyphenyl)-2,2′:6′,2″-terpyridine

RETRACTED: Treatment activity of a new luminescent thermostable Sm(III) complex on preeclampsia

Contact Info

Product

Resources

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Syntheses and Crystal Structures of Ln^III–Cu^I Coordination Polymers

Syntheses and Crystal Structures of Ln^III–Cu^I Coordination Polymers