Synthesis, crystal structure and properties of the new semiconductor (EVT)4·[Pt(CN)4]

Dubrovskiĭ, A. D.; Spitsina, N. G.; Chekhlov, A. N.; D’yachenko, O. A.; Buravov, L. I.; Lobach, Anton; Vidal-Gancedo, José; Rovira, Concepció

doi:10.1016/s0379-6779(03)00353-9

Cited by 5 publications

(5 citation statements)

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“…Several examples of TCP compounds with sulfur‐containing organic conductors such as tetrathiafulvalene have been studied 70–72. Single‐crystal studies of this family of complexes demonstrate that the TCP units do not have any direct Pt–Pt overlap and conduction occurs purely through the organic cations 73–76…”

Section: Complexes With Pt–c Bondsmentioning

confidence: 99%

Platinum Stacking Interactions in Homoleptic Platinum Polymers

Anderson

Hurst

2009

Eur J Inorg Chem

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Recent breakthroughs in low‐dimensional nanostructures have led to a renewal of interest in polymers composed of platinum complexes. The surge of research into one‐dimensional platinum complexes in the 1970s and 1980s has given way to a steady progression of investigations that have explored new ligands, characterization techniques and applications. The ongoing synthesis and characterization of new tetra(cyano)platinate, bis(oxalato)platinate and other homoleptic platinum complexes has allowed examination of the influence of organic and inorganic cations on the Pt–Pt distance and the importance of small molecules in stabilizing the stacking interactions. In particular, complexes of [Pt(C≡NR)4]2+ and [PtI(bipy)2]+ show potential to display short stacking interactions. This microreview focuses on the progress in the synthesis and characterization of homoleptic complexes with short Pt–Pt distances and avenues for the development of new classes of complexes.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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Section: Complexes With Pt–c Bondsmentioning

confidence: 99%

Platinum Stacking Interactions in Homoleptic Platinum Polymers

Anderson

Hurst

2009

Eur J Inorg Chem

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“…On the other hand, the structurally related but unsaturated compounds bis-vinylenedithio-tetrathiafulvalene ( BVDT-TTF ) and ethylene-vinylenedithio-tetrathiafulvalene ( EVT-TTF ) have been far less reported in the literature. On the Scifinder database, over 5000 papers are reported for BEDT-TTF , while only 16 and 7 scientific reports do exist for BVDT-TTF 21–31 and EVT-TTF , 27,32–37 respectively. Amongst these, only 2 papers reported the X-ray structures of single-crystals for BVDT-TTF salts (PF 6 − ) 25,27 and two for EVT-TTF salts (PF 6 − , AsF 6 − , and Pt(CN) 4 2− ) 27,36 despite the fact that early reports described conductive salts, though without structures, with the ReO 4 − , ClO 4 − or I 3 − anions, amongst others.…”

Section: Introductionmentioning

confidence: 99%

“…On the Scifinder database, over 5000 papers are reported for BEDT-TTF , while only 16 and 7 scientific reports do exist for BVDT-TTF 21–31 and EVT-TTF , 27,32–37 respectively. Amongst these, only 2 papers reported the X-ray structures of single-crystals for BVDT-TTF salts (PF 6 − ) 25,27 and two for EVT-TTF salts (PF 6 − , AsF 6 − , and Pt(CN) 4 2− ) 27,36 despite the fact that early reports described conductive salts, though without structures, with the ReO 4 − , ClO 4 − or I 3 − anions, amongst others. Nogami et al reported in a comparative study that the two-dimensional nature of the band structure is increasing in the series BVDT-TTF – EVT-TTF – BEDT-TTF along with the loss of unsaturation.…”

Section: Introductionmentioning

confidence: 99%

“…[16][17][18][19][20] On the other hand, the structurally related but unsaturated compounds bis-vinylenedithio-tetrathiafulvalene (BVDT-TTF) and ethylene-vinylenedithio-tetrathiafulvalene (EVT-TTF) have been far less reported in the literature. On the Scifinder database, over 5000 papers are reported for BEDT-TTF, while only 16 and 7 scientific reports do exist for BVDT-TTF [21][22][23][24][25][26][27][28][29][30][31] and EVT-TTF, 27,[32][33][34][35][36][37] respectively. Amongst these, only 2 papers reported the X-ray structures of single-crystals for BVDT-TTF salts (PF 6 À ) 25,27 and two for EVT-TTF salts (PF 6 À , AsF 6…”

Section: Introductionmentioning

confidence: 99%

“…, and Pt(CN) 4 2À ) 27,36 despite the fact that early reports described conductive salts, though without structures, with the ReO 4 À , ClO 4…”

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confidence: 98%

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