Synthesis, crystal structure and magnetic property of an iron(III) coordination polymer with N-acyl-salicylhydrazide ligand

Qin, Suni; Zu, Chao; Chen, Zilu; Huang, Wentao; Qin, Jiang-Ke; Liang, Fu‐Pei

doi:10.1016/j.inoche.2011.03.066

Cited by 4 publications

(1 citation statement)

References 30 publications

(29 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…For the use of N-acylsalicylhydrazide in the construction of polynuclear complexes and metallacrown structures, see: Liu et al (2008); Moon et al (2006); Qin et al (2011); Wang et al (2005). For applications of complexes with N-acylsalicylhydrazide ligands, see: Alexiou et al (2003); Li et al (1996); Zeng et al (2007); Zhou et al (2010).…”

Section: Related Literaturementioning

confidence: 99%

Bis[μ-N′-(adamantan-1-ylcarbonyl)-2-oxidobenzohydrazidato(3−)]tetrapyridinetrinickel(II) dimethylformamide monosolvate monohydrate

et al. 2012

View full text Add to dashboard Cite

In the title trinuclear NiII compound, [Ni3(C18H19N2O3)2(C5H5N)4]·C3H7NO·H2O, three NiII cations are bridged by two N′-(adamantan-1-ylcarbonyl)-2-oxidobenzohydrazidate trianions. The central NiII cation has a distorted octahedral N4O2 coordination environment where a reverse torsion occurs between the two bridging ligands, whereas the two NiII cations on the sides each adopt an N2O2 square-planar coordination. Weak intramolecular C—H⋯O and C—H⋯N interactions help to stabilize the molecular structure. In the crystal, the lattice water molecule links with the NiII complex and dimethylformamide solvent molecule via O—H⋯O hydrogen bonding.

show abstract