Synthesis, crystal growth and characterization of novel semiorganic nonlinear optical crystal: Dichloro(beta-alanine)cadmium(II)

Ignatius, I. Cicili; Rajathi, S.; Kirubavathi, K.; Selvaraju, K.

doi:10.1016/j.ijleo.2014.04.074

Cited by 14 publications

(3 citation statements)

References 12 publications

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“…The laser triggered breakdown inside the crystals caused by the different physical process which includes multiphoton absorption, photo ionization, and electron avalanche for the transparent material while in case of excessive adsorbing materials, the damage threshold is especially because of the temperature rise which results in the strain‐induced fracture, it additionally depends upon the unique properties of materials pulse width, and wavelength of the laser used . The laser damage threshold (LDT) studies were carried out for the grown KSO single crystal using a Q‐switched Nd: YAG laser for 6 ns laser pulses (repetition rate of 10 HZ) at a wavelength of 1064 nm.…”

Section: Resultsmentioning

confidence: 97%

Synthesis and Investigation on Structural, Thermal, Mechanical, Linear Optical, and Nonlinear Optical Nature of Potassium Sulphato Oxalate Single Crystals

Punniyamoorthy¹,

Manimekalai²,

Uma³

et al. 2019

Crystal Research and Technology

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The new semiorganic potassium sulphato oxalate (KSO) single crystals are grown at room temperature by a slow evaporation method using an aqueous solution. The Fourier transform infrared spectroscopy is used to ascertain the various functional groups present in the grown KSO sample. The single crystal X-ray diffractometer (XRD) results confirm the grown KSO crystal is a triclinic structure with lattice parameters a = 6.37Å; b = 7.03Å; c = 10.61Å; and space group P1. Powder XRD study proves the crystallinity and purity of the grown crystal. The optical behaviors of KSO are analyzed by UV-vis-near infrared reflectance (NIR) spectrophotometer. Photoluminescence (PL) studies of KSO reveal its strong green emission at 576 nm. The laser damage threshold (LDT) of the title compound is measured to be 6.135 GW/cm 2 . The thermo gravimetric and differential thermal analysis indicated that KSO is stable up to 103°C. From the Vickers microhardness tester, the mechanical behaviors of the title compound are studied. The frequency conversion property of KSO crystal is analyzed using Kurtz-Perry method, and it is found to be 1.16 times higher than that of the reference potassium dihydrogen phosphate which indicates KSO is well suited for optoelectronic device fabrication. KSO was synthesized [13] using potassium sulphate (analar grade) and oxalic acid (analar grade) in a stoichiometric ratio of 1:1.

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Section: Resultsmentioning

confidence: 97%

Synthesis and Investigation on Structural, Thermal, Mechanical, Linear Optical, and Nonlinear Optical Nature of Potassium Sulphato Oxalate Single Crystals

Punniyamoorthy¹,

Manimekalai²,

Uma³

et al. 2019

Crystal Research and Technology

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“…7−11 Fortunately, some studies indicated that amino acids, such as proline, could help the plants in reducing the harm coming from the cadmium stress. 12−14 Although cadmium is harmful to living things, it is found that the single crystals of cadmium chloride and amino acids (L-proline, 15,16 trans-4-hydroxy-proline, 17 L-arginine, 18 betaalanine, 19 L-alanine, 20 L-valine 21 ) attract a lot of research enthusiasm because of their unique performance as metalloorganic nonlinear optical materials. These metalloorganic materials have both the chemical peculiarities of organics and favorable physical characteristics of inorganics (such as chemical stability, mechanical strength, higher nonlinear optical efficiency, and so on).…”

Section: Introductionmentioning

confidence: 99%

Study on Phase Equilibria of CdCl₂–l-Proline (trans-4-Hydroxy-proline)–H₂O and the Standard Molar Enthalpy of Formation of Cd(C₅H₉NO₂)Cl₂·H₂O and Cd(C₅H₉NO₃)Cl₂

Yang,

Zhang,

Wang

et al. 2023

J. Chem. Eng. Data

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The solubility of the ternary system of CdCl 2 −L-proline (trans-4-hydroxy-proline)−water at 298.1 K was studied by the isothermal dissolution equilibrium method, and two ternary phase diagrams were drawn. Two double salts (Cd(C 5 H 9 NO 2 )Cl 2 • H 2 O and Cd(C 5 H 9 NO 3 )Cl 2 ) were synthesized, and both of them were characterized by XRD and TG−DTG. In addition, via designing thermochemical cycles and measuring their enthalpy of solution, the standard molar enthalpies of formation of Cd(C 5 H 9 NO 2 )Cl 2 •H 2 O and Cd(C 5 H 9 NO 3 )Cl 2 at 298.15 K were obtained, which were −1225.92 ± 2.19 and −1073.06 ± 1.87 kJ• mol −1 , respectively.

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“…Cd serves as a catalytic center in carbonic anhydrase [5]. Also, it has interesting DNA binding abilities [6][7][8], antibacterial activities [9,10] and antitumor properties [11,12] and is a known catalyst for organic transformations [13][14][15][16][17][18]. Also, Cd(II) compounds have many applications in photoluminescence and non-linear optics [19][20][21][22].…”

Section: Introductionmentioning

confidence: 99%

X-ray Structures and Hirshfeld Studies of Two Dinuclear Cd(II) Complexes with a s-Triazine/Pyrazolo Ligand and Pesudohalides as a Linker

et al. 2023

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The two dinuclear Cd(II) complexes [Cd(BPMST)(SCN)]2 (1) and [Cd(BPMST)(N3)Cl]2 (2) of a s-triazine/pyrazolo ligand (BPMST) were synthesized. The preparation of both complexes was performed in a water–ethanol solvent mixture and involved the mixing of the functional ligand BPMST with CdCl2 in the presence of thiocyanate or azide as linkers, respectively. The dinuclear formula of both complexes and the involvement of the pesudohalide as a linker between the Cd(II) centers were approved by single crystal X-ray structures. The Cd(II) was hexa-coordinated and the CdN5S (1) and CdN5Cl (2) coordination environments had distorted octahedral geometry. In the [Cd(BPMST)(SCN)]2 and [Cd(BPMST)(N3)Cl]2, the BPMST acted as a pincer tridentate N-chelate. In the case of 1, the SCN¯ acted as a μ(1,3) bridging ligand between the Cd(II) centers, while the N3¯ had a μ(1,1) bridging mode in 2. As a result, the Cd…Cd distance was significantly longer in 1 (5.8033(5) Å) than in 2 (3.796(2) Å). In both complexes, the Cd(II) had distorted octahedral coordination geometry. Hirshfeld surface analysis was performed to inspect the supramolecular aspects of the two Cd(II) complexes. The C…H, N…H and S…H contacts were important in the case of [Cd(BPMST)(SCN)]2 (1). Their percentages were calculated to be 14.7, 17.0 and 13.4%, respectively. In the case of [Cd(BPMST)(N3)Cl]2 (2), the most significant contacts were the Cl…H, C…H and N…H contacts. Their contributions in the molecular packing were 16.5, 9.7 and 25.3%, respectively. The propensity of atom pairs of elements to form contacts in the crystal structure was analyzed using enrichment ratio (EXY).

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Synthesis, crystal growth and characterization of novel semiorganic nonlinear optical crystal: Dichloro(beta-alanine)cadmium(II)

Cited by 14 publications

References 12 publications

Synthesis and Investigation on Structural, Thermal, Mechanical, Linear Optical, and Nonlinear Optical Nature of Potassium Sulphato Oxalate Single Crystals

Synthesis and Investigation on Structural, Thermal, Mechanical, Linear Optical, and Nonlinear Optical Nature of Potassium Sulphato Oxalate Single Crystals

Study on Phase Equilibria of CdCl₂–l-Proline (trans-4-Hydroxy-proline)–H₂O and the Standard Molar Enthalpy of Formation of Cd(C₅H₉NO₂)Cl₂·H₂O and Cd(C₅H₉NO₃)Cl₂

X-ray Structures and Hirshfeld Studies of Two Dinuclear Cd(II) Complexes with a s-Triazine/Pyrazolo Ligand and Pesudohalides as a Linker

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Synthesis, crystal growth and characterization of novel semiorganic nonlinear optical crystal: Dichloro(beta-alanine)cadmium(II)

Cited by 14 publications

References 12 publications

Synthesis and Investigation on Structural, Thermal, Mechanical, Linear Optical, and Nonlinear Optical Nature of Potassium Sulphato Oxalate Single Crystals

Synthesis and Investigation on Structural, Thermal, Mechanical, Linear Optical, and Nonlinear Optical Nature of Potassium Sulphato Oxalate Single Crystals

Study on Phase Equilibria of CdCl2–l-Proline (trans-4-Hydroxy-proline)–H2O and the Standard Molar Enthalpy of Formation of Cd(C5H9NO2)Cl2·H2O and Cd(C5H9NO3)Cl2

X-ray Structures and Hirshfeld Studies of Two Dinuclear Cd(II) Complexes with a s-Triazine/Pyrazolo Ligand and Pesudohalides as a Linker

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Study on Phase Equilibria of CdCl₂–l-Proline (trans-4-Hydroxy-proline)–H₂O and the Standard Molar Enthalpy of Formation of Cd(C₅H₉NO₂)Cl₂·H₂O and Cd(C₅H₉NO₃)Cl₂