Synthesis, characterization and spectral studies of nitrogen base adducts of bis(O,O′-ditolyldithiophosphato)nickel(II). Crystal structures of Ni[S2P(OC6H4Me-p)2]2·C10H8N2 and Ni[S2P(OC6H4Me-o)2]2·C14H12N2·C6H6

O,O′-Dimethyl diphenyldithiophosphates of nickel(II) with N-donor ligands

“…Selected bond distances and bond angles for the complexes 1-4 are listed in Tables 1, 2, 3 and 4. In the complexes 1, 2, 3 and 4, the Ni-N1 bond distances are 2.0961(17), 2.108(2), 2.108(12), and 2.098(2) Å , which are comparable with the corresponding octahedral Ni-N bond distances reported for Ni[S 2 P(OC 6 H 4 Me-p) 2 ] 2 (C 10 H 8 N 2 ) (2.060(1) Å ) [14] and [[ (3,5- [30]. The Ni-S1 and Ni-S2 bond lengths for the complex 1 are 2.5061 (5) [10].…”

“…The characteristic stretching bands in the IR spectra were assigned by comparison with literature data [10,14,29,30]. In the complex 4 the band at 1120 and 854 cm -1 may be ascribed to the [m(P)-O-C] and [mP-O-(C)] vibrations of the diphenyldithiophosphate moiety, respectively.…”

“…°and 112.54(3)°, complex 2 are 82.72(2)°and 112.44(4)°, complex 3 are 82.46(11)°and 113.5(2)°, and complex 4 are 83.17(2)°and 114.02 (4)°are in reasonable proximity with that of Ni[S 2 P(OC 6 H 4 Mep) 2 ] 2 (C 10 H 8 N 2 ) [81.33(2)°and 110.34(2)°][14] and [[(3,4- …”

“…The homoleptic dithiophosphates Ni[S 2 P(OR) 2 ] 2 (R = Me [4], Et [5], n-Pr [6], iso-Pr [7], iso-Bu [8], cyclo -C 6 H 11 [9], benzyl, ortho-tolyl, meta-tolyl [10], para-tolyl [11] ) are square-planar complexes. Many six-coordinated adducts like Ni[S 2 P(OR) 2 ] 2 Á2L (L = pyridine [12,13], 2,2 0 -bipyridyl [14], 1,10-phenanthroline [15][16][17][18], 2,9-dimethyl-1,10-phenanthroline [19] ) have been reported. Few five coordinated adducts like Ni[S 2 P(OR) 2 ]Á2L (R = Et; L = PPh 3 [20] or quinoline [16]) are also known.…”

Synthesis and Spectroscopic Characterization of Eight Chloro Cyclopentadienyl Titanium Bis (O, O-Dialkyl and Alkylene Dithiophosphate) Compounds

“…Dithiophosphate complexes of both transition and non-transition elements have received considerable interest due to their wide diversity in chemical [1]- [6] and biological systems [7] [8] O, O-Dialkyl and alkylene dithiophosphate ligands can coordinate to metal atoms in a monodentate or anisobidentate fashion [9] [10]. More recent applications of thio compounds are in the production of nanoparticles of metal sulfides [11] [12].…”