Synthesis, Characterization, and Reactivity Studies of para-Substituted Triaryltin Cobaloximes

Abstract

Synthesis, Characterization, and Reactivity Studies of para-Substituted Triaryltin Cobaloximes Elizabeth Marie Ward Several six-coordinate cobaloxime compounds containing a triaryltin ligand were synthesized and characterized. These cobaloximes include (4-t-BuPy)Co(DH)2Sn(C6H4-ptolyl)3, (4-t-BuPy)Co(DH)2Sn(C6H4-p-t-Bu)3, (NH3)Co(DH)2SnPh3, and (4-t-BuPy)Co(DH)2Bn. (4-t-BuPy)Co(DH)2Sn(C6H4-p-tolyl)3 crystallized in the centrosymmetric triclinic space group P-1 (Z=4) with unit cell dimensions a = 13.2949(5)