Synthesis, characterization and luminescence properties of azobenzene based heterobimetallic Ru(II)/M(II) (M = Ni and Zn) hybrid complexes composed of organometallic and coordination sites

Chavan, S.S.; Lolage, S.R.; Pawal, S.B.

doi:10.1016/j.jorganchem.2016.04.030

Cited by 11 publications

(4 citation statements)

References 37 publications

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“…It has been already proven that the abovementioned properties allow for significant values of first molecular hyperpolarizability β [ 10 , 11 ]. Bis(8-Hydroxyquinoline) zinc—Znq 2 , bis(8-Hydroxyquinoline) copper (II)—Cuq 2 , and tris(8-Hydroxyquinoline) aluminum—Alq 3 have been widely investigated in recent years as organometallic compounds with potential applications in modern optoelectronics [ 12 , 13 , 14 , 15 , 16 ]. The organometallic complexes combine the advantages of organic and inorganic materials, such as an ease of fabrication, architectural flexibility, excellent temporal as well as physical ruggedness, and high resistance to laser light [ 17 , 18 , 19 ].…”

Section: Introductionmentioning

confidence: 99%

Selected Organometallic Compounds for Third Order Nonlinear Optical Application

et al. 2019

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In this paper, we present the third harmonic generation response of Znq2 (Bis-(8-hydroxyquinolinato)zinc), Cuq2 (8-Hydroxyquinoline copper(II)), and Alq3 (Tris-(8-hydroxyquinoline)aluminum) organometallic compounds. An experiment was conducted for s and p polarizations of incident beam, using the Maker fringes technique. The third order nonlinear susceptibility χ(3) was estimated using the Kubodera and Kobayashi comparative model, on the grounds that presented compounds exhibit high linear absorption of the generated third harmonic wavelength (355 nm). These complexes were deposited as thin films using the physical vapor deposition (PVD) method. Investigated complexes vary in terms of the coordination center and number of quinoline ligands, which visibly influence their nonlinear response. The global hybrid B3LYP functional with the basis set 6-31G(d) was used in computing the linear and non-linear optical properties. The computed γtot value (8765.36 × 10−36 esu for Cuq2) is superior to that of methylene blue (γ = 32.00 × 10−36 esu). The calculated theoretical values were found to be in good agreement with the experimental results.

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Section: Introductionmentioning

confidence: 99%

Selected Organometallic Compounds for Third Order Nonlinear Optical Application

et al. 2019

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“…As shown in Figure b,c, the emission shapes and positions are similar to those of the solid-state emission spectra. The emission maxima of compounds 1 and 2 roughly move in the positive direction with the increase in solvent polarity, especially for compound 2 , which can be ascribed to different intramolecular charge transfer states, energy transfer, and formation of hydrogen bonds between the solvents and excited molecules . For compound 1 , the emission intensity is in the order of CH 2 Cl 2 < CH 3 CN < DMSO < CH 3 OH < DMF; whereas for compound 2 , the order is CH 2 Cl 2 < CH 3 OH < DMF < DMSO < CH 3 CN, demonstrating the different interactions of compounds 1 and 2 with the solvents.…”

Section: Resultsmentioning

confidence: 99%

Blue-Emitting Zero-Dimensional Inorganic–Organic Hybrids Constructed from Beta-Diketonate Ligands and Bulky Organic Cations

Liang

Yan

et al. 2023

Inorg. Chem.

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Two zero-dimensional inorganic−organic hybrids, namely, [C 4 mim][Cd(TCDPPA) 3 ] (1) and [C 4 mpy][Cd(TCDPPA) 3 ] (2), where (TCDPPA) − = 2,2,2-trichloro-N-(di(pyrrolidin-1-yl)phosphoryl)acetamide, (C 4 mim) + = 1-butyl-3-methylimidazolium, and (C 4 mpy) + = 1-butyl-4methylpyridinium, have been synthesized via metathesis reactions and characterized systematically. These ionic cadmium-containing inorganic− organic hybrid compounds are assembled from a bulky organic cation and a complex anion constructed from the chelation of three TCDPPA ligands to one cadmium ion. These compounds possess wide band gaps and emit in the deep-blue region intensely with a quantum yield as high as 34.04%. The success of this work provides a new method for the design and fabrication of high-efficiency blue-emitting materials.

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“…In our earlier studies, our lab reported on some azobenzene based Ni(II)/Ru(II) and Zn(II)/Ru(II) heterobimetallic coordination‐organometallic hybrid complexes derived from the reaction of (R‐C 6 H 4 HC=N(O)C 6 H 3 N=NC 6 H 4 C≡CRu(dppe) 2 Cl)] ( 3‐5 ) with nickel acetate or zinc acetate in presence of 8‐hydroxyquinoline (R= Cl, Br, I). The room temperature luminescence was observed for all complexes which markedly depend on increasing electron‐donating nature of the halide in the complexes . The present work describe the synthesis, characterization, thermal, photophysical and nonlinear optical properties of a series of Ru(II)‐Cu(I) heterobinuclear complexes linked by 1,10 phenonthroline ( phen ) or 2,2'‐ bipyridine ( bipy ) as an ancillary ligand.…”

Section: Introductionmentioning

confidence: 97%

Heterobimetallic Cu(I)/Ru(II) Acetylide Bridged Hybrid Complexes Containing Coordination and Organometallic Sites

2017

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The heterobimetallic complexes [Cu(phen)(NC5H4HC=NC6H4C≡CC6H4C≡CRu(dppe)2Cl)]X (1 a‐4 a) and [Cu(bipy)(NC5H4H C=NC6H4C≡CC6H4C≡CRu(dppe)2Cl)]X (1 b‐4 b) (where X= I, ClO4, BF4, PF6; phen= 1, 10 phenanthroline, bipy= 2, 2′ bipyridine) have been prepared by the reaction of (NC5H4HC=NC6H4C≡CC6H4C≡CRu(dppe)2Cl) with copper salts in presence of phen or bipy as a coligand. Our synthetic attempts and successes are discussed in combination with spectroscopic and electronic characterization of the compounds. Comparison between phen and bipy complexes were studied by thermal and electrochemical analysis where, thermally robust complexes demonstrate quasireversible redox behaviour analogous to CuI/II/RuII/III couple. SEM of representative complexes 2 a and 2 b clarify the average size and morphology of the complexes. Room temperature luminescence influenced by varying coordinating ability of counter anions along with π‐acidic character in green‐yellow region was observed. Solvent dependant emission displays positive solvatochromism at ambient temperature. The second harmonic generation (SHG) efficiency of the complexes was measured by Kurtz‐powder technique indicating that all complexes display the second harmonic generation (SHG) property.

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Synthesis, characterization and luminescence properties of azobenzene based heterobimetallic Ru(II)/M(II) (M = Ni and Zn) hybrid complexes composed of organometallic and coordination sites

Cited by 11 publications

References 37 publications

Selected Organometallic Compounds for Third Order Nonlinear Optical Application

Selected Organometallic Compounds for Third Order Nonlinear Optical Application

Blue-Emitting Zero-Dimensional Inorganic–Organic Hybrids Constructed from Beta-Diketonate Ligands and Bulky Organic Cations

Heterobimetallic Cu(I)/Ru(II) Acetylide Bridged Hybrid Complexes Containing Coordination and Organometallic Sites

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