Synthesis, Characterization and Film Preparation of New Co-Polyimide Based on New 3,5-Diamino- N -(Pyridin-4-Ylmethyl)benzamide, Oda and 6fda

Abstract

This work describes mainly the synthesis and characterization of new co-polyimides obtained from the polycondensation of the dianhydride 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA), 4,4'-oxydianiline (ODA) and the new diamine 3,5-diamino-N-(pyridin-4-ylmethyl)benzamide (PyDA). It describes as the different compositions of ODA and PyDA present in the polymers, produce variation on thermal and mechanical properties, which are important characteristics for the development of future nanocomposites derived from these polymers. Both PyDA monomer and polymers were characterized using FT-IR and NMR (1 H, 13 C, 19 F, dept 135°, COSY, HMBC, HMQC) spectroscopy. The inherent viscosity of polymers is between 0.3 to 1.49 dL/g, they are soluble in aprotic polar solvents, such as: DMSO, DMF and DMA. In addition, all co-polymers showed thermal decomposition temperature and glass transition temperatures above 483 °C and 289 °C, respectively. Mechanical tests under tension of co-polymer films showed Young's modulus between 2.1-3.9 GPa and tensile strength between 35.5 and 120.0 MPa. On the other hand, an increase in crystallinity and hydrophilicity is observed when increasing the amount of pyridinyl groups.

Preparation and characterization of silver self-metallization on polyimide

“…Figure 4 also shows that the corresponding peaks became sharp and the peak width became slightly narrower, indicating that the peaks for the crystalline structure of the silver deposits at different times became more vivid. 20,21 The position of the peaks obtained from the diffraction pattern also provides information about the translational size and shape of the crystal. The crystallite size of the silver nanoparticles was calculated using Scherrer's equation D ¼ 0:9 λ βcosθ , where λ is the wavelength of X-ray, β is the width at half maximum height and θ is the Bragg's angle.…”

“…Figure 4 also shows that the corresponding peaks became sharp and the peak width became slightly narrower, indicating that the peaks for the crystalline structure of the silver deposits at different times became more vivid. 20,21…”

Novel Polyelectrolytes Obtained by Direct Alkylation and Ion Replacement of a New Aromatic Polyamide Copolymer Bearing Pyridinyl Pendant Groups

“…PyMDA monomer was obtained by following a two-step protocol previously reported [ 36 ]. In a first step, the direct reaction between 3,5-dinitrobenzoyl chloride and pyridin-4-ylmethanoamine takes place, allowing the obtainment of 3,5-dinitro- N -(pyridin-4-ylmethyl)benzamide.…”