Synthesis, characterization and end use evaluation of 2-allyl-3(5)-pentadecyl phenol and their acrylic/methacrylic esters

Rupavani, J.N.; Vijayalakshmi, V.; Sitaramam, B. S.; Krishnamurti, N.

doi:10.1016/0014-3057(93)90340-l

Cited by 3 publications

(3 citation statements)

References 3 publications

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“…SI‐ATRP results in grafting of polymer chains on to the filler surface and significantly alters the dynamics and mechanical properties of the polymer . The most important physical property that gets affected is the glass transition ( T g ) and has been widely reported, both theoretically and experimentally . The heating and cooling thermograms of the graphene‐PDPMA polymer nanocomposites as obtained from DSC analysis are shown in Figure .…”

Section: Resultsmentioning

confidence: 99%

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Comb‐like polymer‐graphene nanocomposites with improved adhesion properties via surface‐initiated atom transfer radical polymerization (SI‐ATRP)

Nutenki

Suresh

Sreedhar

2017

J of Applied Polymer Sci

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The synthesis and properties of comb‐like polymer‐graphene nanocomposites via surface initiated atom transfer radical polymerization is reported. The crystallization temperature (Tc) and melt temperature (Tm) of the comb‐like homopolymer increases from −18 to −8 °C and 1 to 11 °C, respectively, in the nanocomposite synthesized with 0.6 wt % graphene initiator. The rheological properties like modulus and complex viscosity of the nanocomposite show a twofold increase. Transmission electron microscopy results of the nanocomposite show a well‐intercalated structure with nanoscale distribution of graphene domains and in scanning electron microscopy a sheet‐like structure with corrugations, and crumples are seen. The hydrophobicity, as measured by water contact angle, increases from 101° in the homopolymer to 118° in the nanocomposite. The nanocomposites exhibit substantial increase in adhesive strength on different substrates, with peel strength increasing by more than 1000 times, as compared to the homopolymer. The improved tack and adhesion properties of the nanocomposites suggest them as novel materials for adhesive applications. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 45885.

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Section: Resultsmentioning

confidence: 99%

“…Triethylamine was purchased from Spectrochem, Mumbai, India. The monomer, PDPMA was prepared from methacryloyl chloride and pentadecyl phenol using the procedure reported earlier . The general procedure used for the monomer synthesis as well as its spectral data are given in Supporting Information.…”

Section: Methodsmentioning

confidence: 99%

Comb‐like polymer‐graphene nanocomposites with improved adhesion properties via surface‐initiated atom transfer radical polymerization (SI‐ATRP)

Nutenki

Suresh

Sreedhar

2017

J of Applied Polymer Sci

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“…3-Pentadecylphenol (C 21 H 36 O , 1d). , Cardanol 1 (20 g), absolute ethanol (25 mL), and Pd/C 5% (2 g) were introduced into an autoclave. The mixture was put under hydrogen pressure (5 × 10 6 Pa) and shaken at room temperature for 20 h. After filtration, evaporation of the solvent, and distillation under vacuum, 1d was obtained as a white solid (12.9 g, 65%, bp = 176 °C/0.014 Pa; mp = 49.7 °C).…”

Section: Methodsmentioning

confidence: 99%

Grafted Self-Assembled Monolayers Derived from Naturally Occurring Phenolic Lipids

Pillot¹,

Birot²,

Tran³

et al. 2005

Langmuir

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Self-assembled monolayers grafted onto silicon surfaces were obtained from the hydrosilylation products by trialcoxysilanes of naturally occurring phenolic lipid allyl ethers. The as-obtained materials were characterized by various physical and physicochemical methods. Thus, contact angles of water drops showed that they possess very high hydrophobicity. Their excellent regularity was corroborated by AFM microscopy. The frequencies of the stretching CH2 infrared modes indicate the presence of alkyl chains mainly in the trans/trans conformation. Additionally, optical ellipsometry and quartz microbalance measurements enabled us to estimate the thickness of the films. The results, as a whole, are in good agreement with the formation of densely packed monolayers.

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Valorization of Madagascar’s CNSL via the synthesis of one advanced intermediate (3-Pentadecylcyclohexanone)

Rahobinirina

Rakotondramanga

Berlioz‐Barbier

et al. 2017

Tetrahedron Letters

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Synthesis, characterization and end use evaluation of 2-allyl-3(5)-pentadecyl phenol and their acrylic/methacrylic esters

Cited by 3 publications

References 3 publications

Comb‐like polymer‐graphene nanocomposites with improved adhesion properties via surface‐initiated atom transfer radical polymerization (SI‐ATRP)

Comb‐like polymer‐graphene nanocomposites with improved adhesion properties via surface‐initiated atom transfer radical polymerization (SI‐ATRP)

Grafted Self-Assembled Monolayers Derived from Naturally Occurring Phenolic Lipids

Valorization of Madagascar’s CNSL via the synthesis of one advanced intermediate (3-Pentadecylcyclohexanone)

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