Synthesis, characterization and electrochemical properties of a novel triphosphate LiFe2P3O10

Kopeć, Monika; Ramana, C. V.; Zhang, X.; Mauger, A.; Giligny, François; Morhange, J. F.; Zaghib, Karim; Julien, C.

doi:10.1016/j.electacta.2009.04.050

Cited by 7 publications

(2 citation statements)

References 25 publications

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“…Kanonerovite, Na 3 MnP 3 O 10 ·12H 2 O, is a natural triphosphate mineral [2]; few other synthetic triphosphates have been reported in the literature: Na 3 [7], LiM 2 P 3 O 10 , M = Co and Ni [8,9], RbBe 2 P 3 O 10 [10], Cs 2 MP 3 O 10 (M = Ga, Al, Cr) [11]. These latter ternary phosphates, with the frameworks consisting in associated [PO 4 ] and [MO 6 ], are efficiently used for waste storage hosts [12].…”

Section: Introductionmentioning

confidence: 99%

Na₃MP₃O₁₀·12H₂O (M = Co, Ni): Crystal Structure and IR Spectroscopy

Azzaoui

Essehli

Mejdoubi

et al. 2012

International Journal of Inorganic Chemistry

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Two new dodecahydrate trisodium triphosphates Na 3 MP 3 O 10 · 12H 2 O (M = CO (1), Ni (2)) were synthesized using a wet chemistry route and characterized by X-ray diffraction and FT-IR spectroscopy. They are isotypic, monoclinic (P21/n, Z = 2), with pseudoorthorhombic unit cell parameters ( Å , • ): (a = 14, 9906 (4), b = 9, 1628 (2), c = 14, 6660 (4), β = 90, 098 (2), for (1) and a = 15, 0236 (3), b = 9, 1972 (2), c = 14, 6654 (3), β = 90, 0492 (16) for (2)). Values of R/Rw are 0.0267/0.0738 and 0.0284/0.0907, respectively, for (1) and (2). Both compounds were found to be systematically twinned by 180 • rotation around a. Their frameworks are made by slabs parallel to ab plane, resulting from the cohesion of two kinds of metallic chains. IR spectrum confirms the presence of characteristic bands from P 3 O 10 phosphate group.

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Section: Introductionmentioning

confidence: 99%

Na₃MP₃O₁₀·12H₂O (M = Co, Ni): Crystal Structure and IR Spectroscopy

Azzaoui

Essehli

Mejdoubi

et al. 2012

International Journal of Inorganic Chemistry

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“…Padhi first demonstrated that orthorhombic LiFePO 4 could be used as a cathode for rechargeable Li-ion batteries [6]. In particular, the olivine type LiFePO 4 (triphylite) has attracted much attention as a suitable cathode material [9,60]. LiFePO 4 has been extensively studied because of its attractive properties such as inexpensiveness, non toxicity, high theoretical capacity (170mAhg −1 ), excellent cycling and thermal stability [5,8,61,62].…”

Section: Cathode Materialsmentioning

confidence: 99%

Recent Progress in Structural and Electrochemical Properties in Composite Based LiFePO4 Batteries

Tabassam

Manzoor

2015

J. New Mat. Electrochem. Sys.

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This review describes some recent developments in the composite doped cathode materials such as LiCoO2, LiNiO2, LiMn2O4, and LiMnO2 with focus on LiFePO4. Olivine LiFePO4 have attracted considerable attention since last decade because of its promising properties as a cathode material in Li ion based batteries (LIBs), that is, it offers high theoretical capacity, environmental friendliness, and less toxicity. The electrochemical and structural characterization of this system will be discussed in more detail as compared with its other counterpart.

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A novel LiMg2P3O10 microwave dielectric ceramic for ultra-wideband dielectric resonant antennas applications

Jiang,

Du,

et al. 2024

Ceramics International

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Synthesis, characterization and electrochemical properties of a novel triphosphate LiFe2P3O10

Cited by 7 publications

References 25 publications

Na₃MP₃O₁₀·12H₂O (M = Co, Ni): Crystal Structure and IR Spectroscopy

Na₃MP₃O₁₀·12H₂O (M = Co, Ni): Crystal Structure and IR Spectroscopy

Recent Progress in Structural and Electrochemical Properties in Composite Based LiFePO4 Batteries

A novel LiMg2P3O10 microwave dielectric ceramic for ultra-wideband dielectric resonant antennas applications

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Synthesis, characterization and electrochemical properties of a novel triphosphate LiFe2P3O10

Cited by 7 publications

References 25 publications

Na3MP3O10·12H2O (M = Co, Ni): Crystal Structure and IR Spectroscopy

Na3MP3O10·12H2O (M = Co, Ni): Crystal Structure and IR Spectroscopy

Recent Progress in Structural and Electrochemical Properties in Composite Based LiFePO4 Batteries

A novel LiMg2P3O10 microwave dielectric ceramic for ultra-wideband dielectric resonant antennas applications

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Product

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Na₃MP₃O₁₀·12H₂O (M = Co, Ni): Crystal Structure and IR Spectroscopy

Na₃MP₃O₁₀·12H₂O (M = Co, Ni): Crystal Structure and IR Spectroscopy