Synthesis, Characterization and DNA Binding Studies of [Ruthenium(II)(bpy)2L]2+ where L are Derivatives of imidazo[4,5-f]-1,10-phenanthrolines

Abstract

Three novel ruthenium(II) complexes of the general formula [Ru(II)(bpy) 2 L]2+ were synthesized, where L = 1,10-phenanthroline derivatives of position 2 imidazole having 3,4-didecyloxy-phenyl (ddip), 3,4-ditetradecyloxy-phenyl (dtip) and 3,4-dihexadecyloxy-phenyl (dhip Tiga rutenium (II) kompleks baharu, [Ru(II)(bpy) 2 L] 2 + dengan L = 1,10 derivatif-fenantrolina daripada imidazola mempunyai 3,4-didesiloksifenil (L10), 3,4-ditetradesiloksi-fenil (L14) dan 3,4-diheksadisiloksi-fenil (L16) pada kedudukan 2 telah disintesis. Semua kompleks telah dicirikan oleh analisis unsur, spekstroskopi resonans magnet nukleus dan ESI-MS