Synthesis, Characterization and DFT Calculations of Schiff-Base Vanadium(v) Complexes Derived From Salicyldehyde With 1,2-Diaminopropane or 2-Picolylamine
Abstract:Two ligands were derived from two sciff-bases of salicylaldehyde with 1,2-diaminopropane, Sal-DAP (L1) and salicylsaldehyde with 2-picolyamine, Sal-PA (L2) and their novel dioxovanadium complexes were synthesized. The complexes C1, [VO2(Sal-DAP)] and C2, [VO2(Sal-PA)] are characterized by conductivity measurements, magnetic susceptibility, UV-Vis, IR, thermal analysis, 1 H-and 13 C-NMR.The molecular structure of the complexes C1 and C2 were confirmed using the DFT calculation to obtain the optimized geometries… Show more
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