Synthesis, characterization, and density functional theory investigation of (CH₆N₃)₂[NpO₂Cl₃] and Rb[NpO₂Cl₂(H₂O)] chain structures

Abstract

The actinyl tetrachloro complex [An(V/VI)O2Cl4]2-/3- tends to form discrete molecular units in both solution and solid state materials, but related aquachloro complexes have been observed as both discrete coordination compounds...