Synthesis, characterization and crystal structures of Ni(II), Cd(II) complexes with<b><i>N</i></b>-(2-propionic acid)-salicyloyl hydrazone and bipy/phen

Wu, Wang-Ting; He, Shan; Liu, Feng; Chen, Fengying; Wang, Yao‐Yu; Shi, Qi‐Zhen

doi:10.1080/00958970801958519

Cited by 3 publications

(1 citation statement)

References 29 publications

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“…Cd1 ion locates in a center-symmetrical octahedral coordination geometry completed by six monodentate carboxylic groups from different NPA ligands. All the bond lengths of Cd1-O range from 2.2524 Å to 2.2834 Å (Table SI), which is well agreed with the normal distance [18][19]. However, The bond distance of Cd(2)-O(1) (2.8418(30) Å) is obviously longer than that of other Cd-O (2.2524(17)-2.506(2)) distances, suggests a nonnegligible interaction (Fig.…”

Section: Resultssupporting

confidence: 65%

Synthesis, crystal structures, and properties of three metal complexes with N-phenylanthranilic acid

Tan

Xiong

Gao

et al. 2015

Journal of Molecular Structure

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Section: Resultssupporting

confidence: 65%

Synthesis, crystal structures, and properties of three metal complexes with N-phenylanthranilic acid

Tan

Xiong

Gao

et al. 2015

Journal of Molecular Structure

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Synthesis, characterisation and antitubercular activities of a series of pyruvate-containing aroylhydrazones and their Cu-complexes

et al. 2012

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A series of eight pyruvate-based aroylhydrazones was synthesised and characterised. The reaction of the sodium salts of the aroylhydrazones with one equivalent of copper(II) chloride allowed the isolation of neutral 1:1 complexes in which the hydrazones occupy three basal coordination sites of a square pyramidal Cu(II)-centre, with two solvent molecules completing the coordination sphere. Structural details were obtained through the determination of the crystal structures of two representative pyruvate-based aroylhydrazones and three Cu(II) complexes. The evaluation of the antimycobacterial activity of the sodium salts of the eight pryruvate hydrazones showed that the compounds are essentially inactive in their anionic form. The corresponding neutral Cu(II) complexes, however, exhibit promising antimycobacterial activities if tested under high iron (8 μg Fe per mL) conditions. As observed for the related antimycobacterial agent isoniazid, the activity of the complexes decreases if the M. tuberculosis cells are grown under low iron (0.02 μg Fe per mL) conditions. The Cu(II) complexes may thus have a similar mode of action and may require an iron-containing heme-dependent peroxidase for activation.

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Synthesis, Crystal Structure, and DNA-Binding Studies of Transition Metal Complexes with 2′-(4-Dimethylaminobenzylidene)-2-hydroxybenzoylhydrazide

Guo

Wang

Chen

et al. 2012

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-

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Synthesis, characterization and crystal structures of Ni(II), Cd(II) complexes withN-(2-propionic acid)-salicyloyl hydrazone and bipy/phen

Cited by 3 publications

References 29 publications

Synthesis, crystal structures, and properties of three metal complexes with N-phenylanthranilic acid

Synthesis, crystal structures, and properties of three metal complexes with N-phenylanthranilic acid

Synthesis, characterisation and antitubercular activities of a series of pyruvate-containing aroylhydrazones and their Cu-complexes

Synthesis, Crystal Structure, and DNA-Binding Studies of Transition Metal Complexes with 2′-(4-Dimethylaminobenzylidene)-2-hydroxybenzoylhydrazide

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