Synthesis, characterization and crystal structure of a novel 3‐D copper(II) polymer with bent N‐containing ligand

Abstract

An exploration of the mixed-ligand system under hydrothermal condition, has led to the isolation of a 3-Single-crystal X-ray analyses reveal that it crystallizes in the triclinic space group P-1, a = 8.807(4) Å, b =11.139(6) Å, c = 11.291(5) Å, α=75.337 (7), β = 73.584(5), γ= 66.795(5)°. The Cu ІІ ions are linked into an extended 2-D grid net via mp molecules. Further these layers are united together through the bridging L to form a 3-D structure, which exhibits a new 4-connected topological network.