Synthesis, characterization and catalytic activity of copper(II) complexes of 14-membered macrocyclic ligand; 3,10-dialkyl-dibenzo-1,3,5,8,10,12-hexaazacyclotetradecanel/zeolite encapsulated nanocomposite materials

One of the most significant organic transformations in catalyst technology is the selective oxidation of alcohols. The acceleration of catalyst discovery in this field contributes to the economic and environmental impact in the production of useful materials. Heterogeneous catalysts combined with environmentally benign oxidants, such as molecular oxygen and hydrogen peroxide, are major challenges of exploratory research in the oxidation of alcohols. A wide range of recoverable catalysts has now emerged for these oxidation reactions. In this Focus Review, we present an overview of recent developments in immobilized metal catalysts and evaluate the potential of transition metals in the heterogeneously catalyzed oxidation of alcohols.

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Recent Advances in Immobilized Metal Catalysts for Environmentally Benign Oxidation of Alcohols

Matsumoto

Ueno

Wang

et al. 2008

Chemistry An Asian Journal

291

121

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An Overview of Selective Oxidation of Alcohols: Catalysts, Oxidants and Reaction Mechanisms

Zhang

et al. 2015

Catal Surv Asia

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The oxidation of alcohols to carbonyl compounds is one of the most fundamental reactions in synthetic organic chemistry. In order to achieve the realization of dehydrogenation reactions with high atomic efficiency, suitable catalysts and oxidants are considered as the key factors to obtain the optimum activity and aldehydes/ketones selectivity. This review aims to make an overview on the reasonable reaction mechanism and promising catalytic system of alcohols dehydrogenation.

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Synthesis, characterization and catalytic oxidation of tetrahydrofuran with 16-membered pentaazabis(macrocyclic) copper(II) complexes; {[Cu([16]aneN5)]2R}4+ (R = aromatic nitrogen–nitrogen linkers)

Salavati‐Niasari

Mir

2007

J Incl Phenom Macrocycl Chem

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Synthesis, characterization and catalytic activity of copper(II) complexes of 14-membered macrocyclic ligand; 3,10-dialkyl-dibenzo-1,3,5,8,10,12-hexaazacyclotetradecanel/zeolite encapsulated nanocomposite materials

Cited by 41 publications

References 35 publications

Recent Advances in Immobilized Metal Catalysts for Environmentally Benign Oxidation of Alcohols

Recent Advances in Immobilized Metal Catalysts for Environmentally Benign Oxidation of Alcohols

An Overview of Selective Oxidation of Alcohols: Catalysts, Oxidants and Reaction Mechanisms

Synthesis, characterization and catalytic oxidation of tetrahydrofuran with 16-membered pentaazabis(macrocyclic) copper(II) complexes; {[Cu([16]aneN5)]2R}4+ (R = aromatic nitrogen–nitrogen linkers)

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