Synthesis and thermal decomposition of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Pb(II) m-benzenedisulphonates

García, Araceli Ramírez; Laverat, Alejandro Guerrero; Prudencio, C.Victoria Ragel; Méndez, Antonio Jerez

doi:10.1016/0040-6031(93)80016-4

Cited by 6 publications

(3 citation statements)

References 7 publications

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“…After dehydration at about 100°C, the anhydrous frameworks exhibit significantly increased thermal stability (up to 400°C) relative to the commonly known carboxylate MOFs. have shown that these materials are stable up to 400°C; [6] structural investigations on such compounds have, however, not been made so far. Di-and trisulfonates as linkers in MOFs have so far rarely been reported.…”

Section: Introductionmentioning

confidence: 95%

Sulfonic Acid Analogs of Terephthalic and Trimesic Acid as Linkers in Metal‐Organic Frameworks – Synthesis of Thermally Robust MOFs

et al. 2009

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Section: Introductionmentioning

confidence: 95%

Sulfonic Acid Analogs of Terephthalic and Trimesic Acid as Linkers in Metal‐Organic Frameworks – Synthesis of Thermally Robust MOFs

et al. 2009

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“…The thermal decomposition of coordination compounds with simple organic ligands emerged as a method of choice due to the low reaction temperatures [52][53][54][55][56][57][58]. Metal carbonyls, metal carboxylates, and metal acetylacetonates were recognized as precursors to fabricate nanostructured magnetic oxides with uniform and narrow size distribution of nanoparticles, due to their high purity and cheap production [59][60][61][62][63][64][65].…”

Section: Introductionmentioning

confidence: 99%

BaTiO3/NixZn1−xFe2O4 (x = 0, 0.5, 1) Composites Synthesized by Thermal Decomposition: Magnetic, Dielectric and Ferroelectric Properties

et al. 2023

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To investigate the influence of spinel structure and sintering temperature on the functional properties of BaTiO3/NixZn1−xFe2O4 (x = 0, 0.5, 1), NiFe2O4, ZnFe2O4, and Ni0.5Zn0.5Fe2O4 were in situ prepared by thermal decomposition onto BaTiO3 surface from acetylacetonate precursors. As-prepared powders were additionally sintered at 1150 °C and 1300 °C. X-ray powder diffraction (XRPD) and scanning electron microscopy (SEM) coupled with electron dispersive spectroscopy (EDS) were used for the detailed examination of phase composition and morphology. The magnetic, dielectric, and ferroelectric properties were investigated. The optimal phase composition in the BaTiO3/NiFe2O4 composite, sintered at 1150 °C, resulted in a wide frequency range stability. Additionally, particular phase composition indicates favorable properties such as low conductivity and ideal-like hysteresis loop behavior. The favorable properties of BaTiO3/NiFe2O4 make this particular composite an ideal material choice for further studies on applications of multi-ferroic devices.

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“…Although many synthetic approaches were developed [31][32][33][34][35][36][37][38][39], emphasis should be pointed out to thermal decomposition of suitable precursors for the preparation of functional oxide nanomaterials with tailored properties at mass scale [40]. Coordination compounds, such as metal carbonyls, metal acetylacetonates, and metal carboxylates, have been profoundly investigated as precursors to fabricate nanostructured metal oxides with desired morphology by thermal decomposition [40][41][42][43][44][45][46][47]. Organic solvents are widely used in thermal decomposition methods, to lower reaction temperatures and provide uniform and narrow size distribution of nanoparticles [40,48].…”

Section: Introductionmentioning

confidence: 99%

One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles

et al. 2020

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This work is the first report of a very simple and fast one-pot synthesis of nickel oxide (NiO) and hematite (?-Fe2O3) nanoparticles by thermal decomposition of transition metal aqua complexes with camphor sulfonate anions. Obtained nanopowders were characterized by X-ray powder diffraction, Fourier transform IR analysis, scanning electron microscopy, and Energy-dispersive X-ray spectroscopy. X-ray powder diffraction confirmed the formation of high purity NiO and ?-Fe2O3 crystal phases. In the case of ?-Fe2O3, about five times larger average crystallite size was obtained. Fourier transform IR spectra of synthesized materials showed characteristic peaks for NiO and ?-Fe2O3 nanostructures. To visualize the morphology and the chemical composition of the final products Scanning electron microscopy and Energy-dispersive X-ray spectroscopy were performed. The thermogravimetric analysis was done for a better understanding of the general thermal behavior of precursor compounds. This easy-to-perform and fast preparation method opens a broad range of obtained materials? usage, particularly due to its economic viability

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Synthesis and thermal decomposition of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Pb(II) m-benzenedisulphonates

Cited by 6 publications

References 7 publications

Sulfonic Acid Analogs of Terephthalic and Trimesic Acid as Linkers in Metal‐Organic Frameworks – Synthesis of Thermally Robust MOFs

Sulfonic Acid Analogs of Terephthalic and Trimesic Acid as Linkers in Metal‐Organic Frameworks – Synthesis of Thermally Robust MOFs

BaTiO3/NixZn1−xFe2O4 (x = 0, 0.5, 1) Composites Synthesized by Thermal Decomposition: Magnetic, Dielectric and Ferroelectric Properties

One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles

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