Synthesis and structure of the first platinum(II) pivalato complexes

Черкашина, Н. В.; Kozitsyna, N. Yu.; Александров, Г. Г.; Варгафтик, М. Н.; Моисеев, И. И.

doi:10.1070/mc2002v012n02abeh001549

Cited by 12 publications

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“…Earlier we used PAB as starting material in the synthesis of the platinum(II) mixed-ligand complex Pt II 4 (OOCMe) 4 (OOC t Bu) 4 and platinum(III) lantern complex Pt III 2 (OOCMe) 4 (O 3 SMe) 2 . , In this work, we prepared with the use of PAB the new platinum homo- and heteronuclear carboxylate complexes Pt II (dipy)(OOCMe) 2 ( 1 ), Pt II (μ-OOCMe) 4 Co II (OH 2 ) ( 2 ), and Pt III 2 (OOCMe) 4 (O 3 SPhMe) 2 ( 3 ) and established their structure by single-crystal X-ray diffraction.…”

Section: Introductionmentioning

confidence: 99%

Platinum Acetate Blue: Synthesis and Characterization

et al. 2014

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Platinum acetate blue (PAB) of the empirical formula Pt(OOCMe)2.5±0.25, a byproduct in the synthesis of crystalline platinum(II) acetate Pt4(OOCMe)8, is an X-ray amorphous substance containing platinum in the oxidation state between (II) and (III). Typical PAB samples were studied with X-ray diffraction, differential thermal analysis-thermogravimetric, extended X-ray absorption fine structure, scanning electron microscopy, transmission electron microscopy, magnetochemistry, and combined quantum chemical density functional theory-molecular mechanics modeling to reveal the main structural features of the PAB molecular building blocks. The applicability of PAB to the synthesis of platinum complexes was demonstrated by the preparation of the new homo- and heteronuclear complexes Pt(II)(dipy)(OOCMe)2 (1), Pt(II)(μ-OOCMe)4Co(II)(OH2) (2), and Pt(III)2(OOCMe)4(O3SPhMe)2 (3) with the use of PAB as starting material.

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Section: Introductionmentioning

confidence: 99%