Abstract:An optically active oligo(m‐benzamide) (OBA1), with a chiral alkyl group on the amide nitrogen and a bithiophene chromophore on the benzene ring by the chain‐growth polymerization of methyl 3‐((S)‐2′‐methylbutylamino)‐5‐(2′′‐(5′′,2′′′‐bithienyl)) benzoate are prepared. In addition, unimer to trimer model compounds (M1, M2, and M3) are synthesized by the iterative ester hydrolysis and dehydration condensation. An optically active oligo(m‐benzamide) with a chiral methoxyethoxyethoxy group (OBA2) is likewise synt… Show more
Pseudo-ladderized polystyrenes could be obtained in high yield by the palladium-catalyzed polymer direct arylation using poly(2-bromostyrene) as a prepolymer.
Pseudo-ladderized polystyrenes could be obtained in high yield by the palladium-catalyzed polymer direct arylation using poly(2-bromostyrene) as a prepolymer.
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