“…The situation was changed when convenient approach to synthesis of the parent anion and its C-aryl derivatives via reaction of decaborane with aldehydes in alkali media was elaborated [66][67][68][69][70][71][72].…”
Section: Silver Complexes With the 1-carba-closo-decaborate Anion [1-mentioning
ianion, the structure of which contains two four-coordinated boron atoms, to very weak M . . . H interactions with the hydride atoms in the case of bulky [3,3 1 -Co(1,2-C 2 B 9 H 11 ) 2 ]´monoanion.
“…The situation was changed when convenient approach to synthesis of the parent anion and its C-aryl derivatives via reaction of decaborane with aldehydes in alkali media was elaborated [66][67][68][69][70][71][72].…”
Section: Silver Complexes With the 1-carba-closo-decaborate Anion [1-mentioning
ianion, the structure of which contains two four-coordinated boron atoms, to very weak M . . . H interactions with the hydride atoms in the case of bulky [3,3 1 -Co(1,2-C 2 B 9 H 11 ) 2 ]´monoanion.
“…2). Consequently, several compounds were obtained directly, such as 1c , 21,22 1d , 23 1e , 18 1f , 24 1g , 25 1h , 24 or through simple chemical transformations ( 1i , 26 1j , 27 and 1k (ref. 24)) and their structures were reported (Fig.…”
Five new structures of the [closo-1-CB9H10]- anion substituted at the apical position(s) are reported expanding the pool of such derivatives to a total of 35. Geometrical features of twenty four...
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