Synthesis and Structure of BiMnVO5 and BiMnAsO5

Bonding Scheme and Optical Properties in BiM2O2(PO4) (M=Cd, Mg, Zn); Experimental and Theoretical Analysis

“…;X = P, As, V) was successfully achieved by tuning the n value. [10][11][12][13][14][15][16][17][18][19] In this paper,t he study of opticalp roperties of the n = 2m embersr epresent the first step for extracting the structural key parameters prior to as ystematization of optical properties as af unctiono fn. Ar ecent report on the optical properties of undoped BiMg 2 (XO 6 )( X= P, V), and dopedw ith trivalent lanthanide ions, established room temperature emission of Bi 3 + ions in this structural type, although the possibility for the presenceo fd efectc enters was argued.…”

“…It is noteworthy that in the past decade the prediction of an extended number of original compounds in the Bi 2 O 3 ‐MO‐X 2 O 5 phase diagrams (M=Cu, Zn, Mn, Mg, etc. ; X=P, As, V) was successfully achieved by tuning the n value . In this paper, the study of optical properties of the n= 2 members represent the first step for extracting the structural key parameters prior to a systematization of optical properties as a function of n .…”

Synthesis, crystal structure and optical properties of BiMgVO5

“…Studies of Bi 2 O 3 -MO-X 2 O 5 (M=Mg, Mn, Co, Ni; X=P, V, As) systems revealed the series of compounds as BiMXO 5 . Crystal structures of BiMPO 5 (M=Mn, Co, Ni) [4][5][6][7][8], BiMVO 5 (M=Ca, Mn, Cd, Pb) [9][10][11][12] and BiMnAsO 5 [10] have been determined. To our knowledge the composition BiMgVO 5 has not been reported.…”

Tv‐tipp

“…A 1:1:2:1 mixture of the starting materials was subsequently heat treated at 550 °C for 60 h. Single crystals were separated manually from unreacted starting material and byproducts. A substantial amount of MnSbVO 5 , which is isostructural to the previously described MnBiVO 5 24 was also formed during the synthesis. Synthesis attempts to vary the Sb/V ratio to x values outside the range 0.08–0.13 were not successful and did not yield single crystals of the aimed phase.…”