Abstract:Abstract:Reaction of NaH with a THF solution of Eu(BTA) 3 (pypzH) 3,pyridine] leads to the formation of the europium-free tetrasodium complex [Na 4 (pypzH) 2 (µ 4 -BTA) 2 (µ 2 -BTA) 2 ]. Single-crystal Xray diffraction studies revealed the presence of a centrosymmetric Na + hybrid tetramer, which fully occupies the contents of the triclinic unit cell. The crystal structure contains two individual Na + cations, Na(1) and Na(2), which have highly irregular {NaN 2 O 3 } and {NaO 6 } local coordination environment… Show more
The oxidative decarbonylation and catalytic chemistry of molybdenum(0) tricarbonyl and tetracarbonyl complexes containing the same diimine ligand are compared.
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