“…Theses features are the result of the tendency of thiolate ligands to bridge metal centers to yield oligomeric (I) : ( ) (1,10-) or polymeric species. 5 On the other hand, the presence of coligands, such as 2,2-bipyridine, 1,10-phenanthroline, bis(diphenylphosphino)methane, etc, might modify such aggregation processes producing binuclear or polynuclear thiolate complexes. 6 When 1,10-phenanthroline reacts with bis(dipropyldithiophosphato) silver(I) in EtOH, we obtained a new dinuclear silver(I) complex, bis(1,10-phenanthroline) bis(dipropy ldithiophosphato) disilver(I).…”