2005
DOI: 10.1002/chin.200511032
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Synthesis and Structural Characterization of a Novel Type of Heteropolyanion: [Sb4Mo12(OH)6O48]10-.

Abstract: Molybdenum I 5600 Synthesis and Structural Characterization of a Novel Type of Heteropolyanion: [Sb4Mo12(OH)6O48] 10-. -The novel antimony substituted polyoxomolybdate (III) crystallizes in the monoclinic space group C2/c with Z = 4 (single crystal XRD). The [Sb4Mo12(OH)6O48] 10anion exhibits a central Sb4(OH)6O14 core where all Sb V atoms are coordinated octahedrally by six oxygen atoms. (III) represents a novel type of heteropolyanion without an analogous structure in the literature. -(DREWES, D.; VOLLMER, G… Show more

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