“…Utilizing carbamate chemistry, − we coassembled hexa-2,4-diyne-1,6-diyl bis((2,2,6,6-tetramethylpiperidinyloxyl)carbamate) (di-TEMPO–DA) and hexa-2,4-diyne-1,6-diyl bis(phenylcarbamate) (diphenyl-DA) in various organic solvents, and this led to supramolecular gelation through the N–H–O hydrogen bonding of the carbamate groups. This type of gelation occurs through the formation of a one-dimensional assembly, which is oft-observed for hydrogen bonded mediated supramolecular gelation .…”