Synthesis and sintering of Li2SnO3

Inagaki, Michio; Nakai, Shigeo; Ikeda, Tadashige

doi:10.1016/0022-3115(88)90051-7

Cited by 16 publications

(7 citation statements)

References 6 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Li 2 SnO 3 with the monoclinic crystal structure ( Figure 1 d) has been known to be a promising potential material for nuclear fusion reactors since their early stages . As a Sn‐based materials, it also shows great potential as an anode material for LIBs with the theoretical capacity of 1246 mAhg −1 .…”

Section: Stannate Anodesmentioning

confidence: 99%

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Zhao

Yan

et al. 2016

Advanced Energy Materials

811

374

View full text Add to dashboard Cite

improved LIB performance is in the electrode materials. [ 11 ] Presently, commercial anode materials mainly include graphite, which limits the lithium storage performance in terms of energy and power density due to the low theoretical capacity (LiC 6 , 372 mAh g −1 ) and low Li-ion transport rate. [12][13][14] New anode materials with higher capacities are being looked for including mixed transition metal oxide anodes. Traditional Metal Oxide AnodesNew research is constantly being carried out to reach the high requirements for LIB anodes. Various metal oxide materials such as SnO 2 , [15][16][17][18][19] Co 3 O 4 , [20][21][22][23] NiO, [24][25][26][27] Fe 3 O 4 , [28][29][30] and MnO 2 [31][32][33] are alternative potential anodes for LIBs due to their high theoretical capacities, high power density, and wide usefulness. However, metal oxides inevitably suffer from several major problems: severe volume changes during the alloying-dealloying processes, pulverization and agglomeration of primitive particles, and poor electronic conductivity that hinders the reaction with lithium during electrochemical reactions. Numerous approaches have attempted to address these challenges. One useful method is to develop the metal oxide materials into nanostructures. [ 3 ] The distinct lithium storage mechanisms and the infl uence of unique structures on the lithium storage properties of the metal oxide materials have been reported in detail. [ 5 ] A series of work on the design of various nanostructures of metal oxide materials has been subsequently carried out, for nanomaterials of different dimensions, hollow structures, and hierarchical structures. [ 5 ] Coating or combining the buffering matrix or conductive materials with metal oxide materials is another way to relieve the severe problems. [36][37][38][39][40][41][42] Various carbon materials, especially novel nanocarbon materials like carbon nanotubes and graphene nanosheets, have been widely studied as the buffering and conductive agent for metal oxide anodes. [43][44][45][46] In our previous review, [ 47 ] the signifi cant effects of graphene nanosheets on tin-based anodes were summarized in detail. It has been concluded that graphene not only contributes as a highly conductive network, but also as a fl exible supporting layer, effectively relieving the volume change and particle aggregation. In addition, different metals and metal oxides that are electrochemically active and Mixed transition-metal oxides (MTMOs), including stannates, ferrites, cobaltates, and nickelates, have attracted increased attention in the application of high performance lithium-ion batteries. Compared with traditional metal oxides, MTMOs exhibit enormous potential as electrode materials in lithium-ion batteries originating from higher reversible capacity, better structural stability, and high electronic conductivity. Recent advancements in the rational design of novel MTMO micro/nanostructures for lithium-ion battery anodes are summarized and their energy storage mechanism is compared to transit...

show abstract

Section: Stannate Anodesmentioning

confidence: 99%

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Zhao

Yan

et al. 2016

Advanced Energy Materials

811

374

View full text Add to dashboard Cite

show abstract

“…Moreover, different synthesis methods, such as hydrothermal method, electrochemical oxidation method, mechanical milling method, electron beam evaporation method, solid‐state reaction method, sol–gel method, and electrodeposition method, can also influence the performance of the negative electrode materials. Li 2 SnO 3 has been successfully prepared by various methods such as a solid‐state reaction route, a sol–gel route and a ball‐milled method and showed good electrochemical properties. Nevertheless, it suffers from low capacity retention.…”

Section: Introductionmentioning

confidence: 99%

Preparation of Li₂SnO₃ and its application in lithium‐ion batteries

Wang

Huang

Zhao

et al. 2013

Surface & Interface Analysis

View full text Add to dashboard Cite

Tin‐based oxide Li2SnO3 has been synthesized by a hydrothermal route as negative material for lithium‐ion batteries. The microstructure and electrochemical properties of the as‐synthesized materials were investigated by some characterizations means and electrochemical measurements. The as‐synthesized Li2SnO3 is a porous rod, which is composed of many uniform and regular nano‐flakes with a size of 50–60 nm. Li2SnO3 also displays an electrochemical performance with high capacity and good cycling stability (510.2 mAh g−1 after 50 cycles at a current density of 60 mA g−1 between 0.0 V and 2.0 V verusus Li/Li+). Copyright © 2013 John Wiley & Sons, Ltd.

show abstract

“…Among the lithium based oxides, Li2SnO3 has aroused increasing attention during the last years due to its applications as dielectric material in the range of microwaves, [1][2][3] breeding material for nuclear fusion reactors, [4,5] and mainly in the field of energy storage owing to its use as electrode in Li-ion batteries. [6][7][8].…”

Section: Introductionmentioning

confidence: 99%

“…[12] Li2SnO3 has been also used as a model in the study of Li diffusion in similar ternary systems. Li2SnO3 is usually synthesized in form of bulk material, [2,12] thin film, or nanoparticles [10,11] by using different approaches such as the hydrothermal method, [9,13] sol-gel technique, [14] thermal decomposition, [4] or solid state reactions [15,16]. There is no with stacking faults along c-axis in Li2SnO3 crystals has already been studied by Tarakina et al [24,25] In that work the authors reported that Li2SnO3 can be synthesized in two phases: the low-temperature Nano Res.…”

Section: Introductionmentioning

confidence: 99%

Li2SnO3 branched nano- and microstructures with intense and broadband white-light emission

et al. 2018

View full text Add to dashboard Cite

show abstract

Synthesis and sintering of Li2SnO3

Cited by 16 publications

References 6 publications

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Preparation of Li₂SnO₃ and its application in lithium‐ion batteries

Li2SnO3 branched nano- and microstructures with intense and broadband white-light emission

Contact Info

Product

Resources

About

Synthesis and sintering of Li2SnO3

Cited by 16 publications

References 6 publications

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Recent Developments and Understanding of Novel Mixed Transition‐Metal Oxides as Anodes in Lithium Ion Batteries

Preparation of Li2SnO3 and its application in lithium‐ion batteries

Li2SnO3 branched nano- and microstructures with intense and broadband white-light emission

Contact Info

Product

Resources

About

Preparation of Li₂SnO₃ and its application in lithium‐ion batteries