Abstract:Protonation of anion 1 [Fe(CO)3(NO)]−, (Na+) in the presence of P(C6H5)3 yielded the iron nitrosyl hydrides 3 FeH-(CO)2(NO)(P(C6H5)3) and 4 FeH(CO)(NO)(P(C6H5)3)2 or the iron nitrosyl cation 5 [Fe(CO)2(NO)(P(C6H5)3)2]+, [Formula: see text] de- pending upon the conditions. Anions 12 (Li+),[Fe(CO)(NO)(P(C6H5)3)2]− and 15 (Li+),[Fe(CO)2(NO)(P(C6H5)3)]− were formed in the reactions of Li+, −HB(C2H5)313 with hydrides 4 and 3 respectively. Anions 15 resulted also from the reaction of cation 5 with an excess (at leas… Show more
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