1976
DOI: 10.1007/bf00906775
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Synthesis and reactions of hydroxylated stilbenes and their possible occurrence as chromophore precursor structures in lignin

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Cited by 14 publications
(3 citation statements)
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“…Model exper- Both the E form (4a) and the Z form (5a) of a stilbene of type (17 have been detected in a kraft pulping liquor (Gierer & Lindeberg, 1980). The steric assignments of (4a) and (5a) are primarily based on the synthetic methods used for their preparation (Nelson & Wallis, 1973;Lonsky et al, 1976). It is notable that the Z H NMR signal from one of the methoxyl groups in the acetate derivative (5b) is located at comparatively high field (6 3.45) .…”
Section: Commentmentioning
confidence: 99%
“…Model exper- Both the E form (4a) and the Z form (5a) of a stilbene of type (17 have been detected in a kraft pulping liquor (Gierer & Lindeberg, 1980). The steric assignments of (4a) and (5a) are primarily based on the synthetic methods used for their preparation (Nelson & Wallis, 1973;Lonsky et al, 1976). It is notable that the Z H NMR signal from one of the methoxyl groups in the acetate derivative (5b) is located at comparatively high field (6 3.45) .…”
Section: Commentmentioning
confidence: 99%
“…The bleaching process of the pulp has attracted significant attention for reducing the release of chemical and energy waste to the environment. In a conventional bleaching process, chromophores such as lignin and its degradation products containing conjugated double bonds that are formed via oxidation during the pulping process [3][4][5][6] are degraded with chlorine reagents such as sodium hypochlorite and chlorine dioxide, resulting in the production of toxic chlorinated compounds [7].…”
Section: Introductionmentioning
confidence: 99%
“…A number of structures have been implicated as c_omophores in mechmcal and chemcal pulps, including: catechol-metal complexes [1][2][3][4], comferaldehyde [1,2,5], quinone methides [1], stable radicals [1] and quinones [1,2,4,[6][7][8][9]. Of the vinous possible chromophores, quinones have been suggested to be major contributors to the color of kraft lignin [6][7][8]10].…”
mentioning
confidence: 99%