Synthesis and properties of RDX/GAP nano-composite energetic materials

Abstract

Fuel or oxidant composites were trapped in the holes of poly(azide glycidyl ether) (GAP) gel skeleton network on nano-scale, which could effectively increase the contact area, decrease the transport distance, and make the energy release more close to the ideal state to achieve the maximum power of energetic materials. In this study, GAP gels with three dimensional nano-network structures were prepared by sol-gel method using GAP as precursors and hexamethylene diisocyanate (HDI) as curing agent. The obtained gels were well characterized by Brunauer-Emmett-Teller (BET).The results showed that the specific surface area and dominant pore size were about 41.78 m 2 /g and 5~30 nm, respectively. Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) could be crystallized in the pore of GAP gel skeleton, so RDX/GAP nanocomposite materials were prepared by solute crystallization in combination with a modified drying technology. The average grain size of RDX in GAP network was 20~46 nm. With the increase of the loadings of RDX, the specific surface area of GAP/RDX nano-composite materials decreased, and the thermal decomposition temperature of RDX in RDX/GAP nanocomposite materials decreased by 33~37°C. The decomposition heat and explosion heat of RDX(40 wt%)/GAP nanocomposite materials were higher by over 13.9 and 19.3 % than those of RDX(40 wt%)/GAP physical blend materials, respectively. Furthermore, the sensitivity of RDX(40 wt%)/GAP nano-composite materials was lower than that of physical blend materials according to the results from our impact sensitivity test.

Facile preparation of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane/glycidylazide polymer energetic nanocomposites with enhanced thermolysis activity and low impact sensitivity

“…The peak at 2084 cm À1 corresponds to the azide groups (-N 3 ). 37,38 Fig. 4(b) shows the FT-IR spectrum of raw HMX.…”

The longstanding challenge of the nanocrystallization of 1,3,5-trinitroperhydro-1,3,5-triazine (RDX)

“…Li et al [ 29 ] used a better energetic matrix, GAP, with a maximum of 40 wt % RDX. They noticed a lower sensitivity than the physical mix.…”

Characteristics and properties of nitrocellulose/glycidyl azide polymer/2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane nanocomposites synthesized using a sol–gel supercritical method

“…Now, some nanocomposites using energetic materials as matrix have been fabricated, such as nitrocellulose (NC)/ HMX, 26 glycidyl azide polymer (GAP)/HMX, 27 and RDX/ GAP. 28 Because it is cheap and easily available, NC is the most widely used as the matrix. However, because NC has a high glass-transition temperature (T g ) and there are lots of rings in its molecules, NC is very crisp and NC-based composites are of very poor mechanical properties in a cold environment, which limits the application of NC-based composites.…”