2016
DOI: 10.1002/adma.201505049
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Synthesis and Properties of Novel Silver‐Containing DNA Molecules

Abstract: Migration of silver atoms from silver nano-particles selectively to a double-stranded poly(dG)-poly(dC) polymer leads to metallization of the DNA. As a result the DNA molecules become shorter and thicker (higher), as evident from the atomic force microscopy imaging analysis. The metalized molecules can be detected by transmission and scanning electron microscopy in contrast to the initial non-metalized ones.

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Cited by 35 publications
(52 citation statements)
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“…Based on observations from transmission electron microscopy, scanning electron microscopy and X-ray photoelectron spectroscopy, silver ions were shown to be deposited on the backbone of the DNA duplex, leading to morphological changes and structural rigidity of DNA molecules. With silver ions, the length and height of the DNA were approximately one third shorter and larger than that of those of native DNA [39].…”
Section: Conductivity Of Dna Nanowiresmentioning
confidence: 89%
See 1 more Smart Citation
“…Based on observations from transmission electron microscopy, scanning electron microscopy and X-ray photoelectron spectroscopy, silver ions were shown to be deposited on the backbone of the DNA duplex, leading to morphological changes and structural rigidity of DNA molecules. With silver ions, the length and height of the DNA were approximately one third shorter and larger than that of those of native DNA [39].…”
Section: Conductivity Of Dna Nanowiresmentioning
confidence: 89%
“…Hence, making DNA conductive is essential for the application of DNA in nanoelectronics. Interestingly, low-conductance linear DNA can be transformed into a highly conductive nanowire by doping metal ions or metallisation [38][39][40]. Metal ions were shown to bind strongly to the base pairs of DNA and are enclosed by the phosphate sugar backbones.…”
Section: Conductivity Of Dna Nanowiresmentioning
confidence: 99%
“…Graphene can also be used as a storage medium for DNA, for hybridization, for address assembly and for the interaction of complementary chains [12]. It is also of interest to cover graphene surface by metallized DNA, which is essentially a molecular wire [1,13]. When applied, the conductivity of both graphene and the DNA molecules may change.…”
Section: Introductionmentioning
confidence: 99%
“…Several types of DNA-based metalized nanowires have been recently reported. Among them are: new metalized form of DNA, E-DNA [1], and thin gold nanoparticlescoated DNA wires [2]. In this work we present direct conductivity measurements of such gold-coated DNA wires.…”
Section: Introductionmentioning
confidence: 99%