Synthesis and properties of ferrocene confined within UiO-67 MOFs

Construction of g‐C3N4‐Ferrocene Copolymers for Enhanced Visible‐Light Photocatalytic Activity

“…Two peaks at 711.2 and 724.5eV in the Fe 2p spectrum corresponded to Fe 2p 3/2 and Fe 2p 1/2 (Figure S1), are typical of ferrocene. [46] To further confirm the incorporation of ferrocene in the network, the high resolution spectra of N 1s of pure g-C 3 N 4 and CNFe-0.02 were shown in Figure S2. There were four peaks at 396.8, 398.6, 400.7 and 404.3 of CNFe-0.02, which represented the C=N bond of the s-triazine ring, bridging N atoms in N-(C) 3 , N atoms in N-H x and the charging effect, respectively.…”

“…The atomic ratio of Fe, C and N were calculated to be about 5.99 %, 56.58 % and 38.43 % from XPS result, respectively. Two peaks at 711.2 and 724.5eV in the Fe 2p spectrum corresponded to Fe 2p 3/2 and Fe 2p 1/2 (Figure S1), are typical of ferrocene [46] …”

Electrochemical Applications of Ferrocene‐Based Coordination Polymers

“…[98,99] In an interesting example, Fc was encapsulated into the micropores of UiO-67 via a solvent-free evaporation method, and the Fc@UiO-67 composite demonstrated good ferromagnetic properties at ambient temperature. [100] High-temperature pyrolysis can be used as a facile and scalable method for the preparation of single Fc molecules trapped in ZIF-8 cavities. [101] On the other hand, Kim et al reported the vapor diffusion-based incorporation of Fc and its derivatives into MOF-5, which has large cavities and wide windows.…”

“…A unified Fc(COOH) 2 /ZIF‐8/3D‐KSCs electrode showed higher performance for the electrochemical sensing of ascorbic acid (AA) than common nonenzymatic sensors and enzyme‐based biosensors [98,99] . In an interesting example, Fc was encapsulated into the micropores of UiO‐67 via a solvent‐free evaporation method, and the Fc@UiO‐67 composite demonstrated good ferromagnetic properties at ambient temperature [100] …”

Ce-doped UiO-67 nanocrystals with improved adsorption property for removal of organic dyes

“…4(c). 40 The binding energy at 533 eV is assigned to the CO groups and the peaks at 533.6 eV correspond to the oxygen of H 2 O. The peaks at 531.7 eV are attributed to the CeO and ZrO.…”