Synthesis and properties of 5-membered heterocyclic disulfides: Application for enzyme modification

Schmidt, Ulrich; Pfleiderer, Gerhard; Bartkowiak, Frank

doi:10.1016/0003-2697(84)90791-7

Cited by 11 publications

(1 citation statement)

References 17 publications

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“…Solvents and reagents were appropriately dried and purified. 1,1'-Diisocyanoferrocene (1), [65] 1,1'-di (methylthio)ferrocene (4), [11] 1,1'-di(phenylthio)ferrocene (5), [11] 1,1'-di(2-thienyl)ferrocene (6), [10] 1,1',2,2'-tetra(methylthio)ferrocene (8), [66] 2,2'-di(thien-2-yl)disulfide, [67] 2,2'-di(thiazol-2-yl)disulfide [68] and 1,1'-bis(triphenylphosphoranylidenamino)ferrocene [8a] were prepared according to, or by slight variation of, published procedures. NMR: Varian Unity INOVA 500 (500.13 MHz for 1 H); IR: BIO-RAD FTS-40A; elemental analyses: microanalytical laboratories of the University of Kassel and of Imperial College London.…”

Section: Methodsmentioning

confidence: 99%

Dipodal Ferrocene‐Based Adsorbate Molecules for Self‐Assembled Monolayers on Gold

Weidner

Ballav

Zharnikov

et al. 2008

Chemistry A European J

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1,1'-Difunctionalised ferrocene derivatives have been studied, which contain groups suitable for chemisorption on gold substrates, namely -NC, -PR(2) as well as a range of sulfur-containing units like -NCS, -SR, and thienyl. Thin films on gold have been fabricated from solution with most of these adsorbate species. Film thickness, composition and structure were investigated primarily by X-ray photoelectron and near-edge X-ray absorption fine-structure spectroscopy. The quality of self-assembled monolayers fabricated from 1,1'-diisocyanoferrocene (1) and 1,1'-diisothiocyanatoferrocene (2) turned out to be superior to that of films based on the other adsorbate species investigated. In addition to the surface coordination behaviour of 1 towards gold substrates, relevant aspects of the molecular coordination chemistry of 1 have also been addressed, including the synthesis and characterisation of [(mu-1){Cr(CO)(5)}(2)], [Ag(2)(mu-1)(2)](NO(3))(2) x H(2)O and [(mu-1)(AuCl)(2)]. The crystal structure of the gold complex is governed by aurophilic interactions and can be taken as a model for the arrangement of 1 in self-assembled monolayers on gold.

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Section: Methodsmentioning

confidence: 99%

Dipodal Ferrocene‐Based Adsorbate Molecules for Self‐Assembled Monolayers on Gold

Weidner

Ballav

Zharnikov

et al. 2008

Chemistry A European J

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Benzoic Acid, 5-[(2-Aminoethyl)dithio]-2-nitro-

Kularatne

2010

Encyclopedia of Reagents for Organic Synthesis

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Thiols and Organic Sulfides

Roy¹

2000

Ullmann's Encyclopedia of Industrial Chemistry

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The article contains sections titled: 1. Aliphatic Thiols, Sulfides, Disulfides, and Polysulfides 1.1. Introduction 1.2. Properties of Aliphatic Thiols 1.2.1. Physical Properties 1.2.2. Chemical Properties 1.3. Production of Aliphatic Thiols 1.3.1. From Alcohols 1.3.2. From Alkenes 1.3.3. Other Production Methods 1.4. Construction Materials, Storage, and Transport 1.5. Uses of Aliphatic Thiols 1.6. Alkyl Sulfides, Disulfides, and Polysulfides 1.6.1. Physical and Chemical Properties 1.6.2. Production of Alkyl Sulfides 1.6.3. Production of Alkyl Disulfides 1.6.4. Production of Alkyl Polysulfides 1.6.5. Uses of Alkyl Sulfides, Disulfides, and Polysulfides 2. Aromatic Thiols, Sulfides, Disulfides, and Polysulfides 2.1. Physical and Chemical Properties 2.2. Production of Aromatic Thiols 2.2.1. By Reduction 2.2.2. By Thiolation 2.3. Uses of Aromatic Thiols 2.4. Production of Aryl Sulfides, Disulfides, and Polysulfides 2.5. Uses of Aryl Sulfides, Disulfides, and Polysulfides 3. Heterocyclic Thiols, Sulfides, and Disulfides 3.1. Introduction 3.2. Physical and Chemical Properties 3.3. Production 3.3.1. Heterocyclic Thiols by Substitution 3.3.2. Heterocyclic Thiols by Cyclization 3.3.3. Heterocyclic Sulfides and Disulfides 3.4. Uses of Heterocyclic Thiols, Sulfides, and Disulfides 3.4.1. Pharmaceuticals 3.4.2. Agricultural Chemicals 3.4.3. Other Uses 4. Toxicology 5. Acknowledgement

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Synthesis and properties of 5-membered heterocyclic disulfides: Application for enzyme modification

Cited by 11 publications

References 17 publications

Dipodal Ferrocene‐Based Adsorbate Molecules for Self‐Assembled Monolayers on Gold

Dipodal Ferrocene‐Based Adsorbate Molecules for Self‐Assembled Monolayers on Gold

Benzoic Acid, 5-[(2-Aminoethyl)dithio]-2-nitro-

Thiols and Organic Sulfides

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