Synthesis and Properties of 2-Alkylene/Dialkyl Dithiophosphato-2-oxo-1,3,2-dioxaphosphorinanes

Harkut, Neelam; Nagar, Pankaj

doi:10.1080/104265090929922

Cited by 8 publications

(3 citation statements)

References 16 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In continuation to our earlier investigations on synthesis and properties of phenyl acetyl, p-methyl benzoyl [11], 2-alkylene dialkyl dithiophosphato-2-oxo-1,3,2-dioxa phosphorinane [12], phosphorus trichloride [13], and thio phosphoryl chloride [14] derivatives of alkylene dithiophosphates, it was considered of interest to extend the investigations on the derivatives of the above ligands with N-bromosuccinimide.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Properties of N-Bromosuccinimide Derivatives of Ammonium Dialkyl/Alkylene Dithiophosphates

Harkut¹,

Nagar²

2007

Bioinorganic Chemistry and Applications

Self Cite

View full text Add to dashboard Cite

Reaction of N-bromosuccinimide with ammonium salt of alkylene (dialkyl) dithiophosphates, [OGOPS2NH4; G=−CMe2CMe2−CH2CMe2CH2−, CMe2CH2CHMe2−, CH2CH2CHMe2−; (RO)2PS2NH4; R=C2H5, n−C3H7, i−C3H7], in 1 : 1 molor ratio in refluxing benzene solution yields red/brown-colored sticky liquids. These newly synthesized complexes have been characterised by physicochemical and spectroscopic techniques (MW, IR, NMR [1H and 31P]). The computational semiempirical calculations (MOPAC6P/c) have also been studied for these complexes. On the basis of the above studies, the formation of P−S−N chemical linkage has been established.

show abstract

Section: Introductionmentioning

confidence: 99%

Synthesis and Properties of N-Bromosuccinimide Derivatives of Ammonium Dialkyl/Alkylene Dithiophosphates

Harkut¹,

Nagar²

2007

Bioinorganic Chemistry and Applications

Self Cite

View full text Add to dashboard Cite

show abstract

“…Dithiolato moieties like dithiocarbamates1–6 and alkylene‐ dithiophosphates7–11 are versatile ligands and display a broad variety of coordination patterns, leading to a great diversity of molecular and supramolecular structures. With regards to structural studies, these ligands often display bidentate coordination patterns, which may be isobidentate (symmetrical) or anisobidentate (unsymmetrical) both in chelating and bridging situations.…”

Section: Introductionmentioning

confidence: 99%

Synthetic, spectral as well as in vitro antimicrobial studies on some bismuth(III) bis(N,N‐dialkyldithiocarbamato) alkylenedithiophosphates

Chauhan¹,

Bakshi²,

Bhatiya³

2010

Applied Organom Chemis

View full text Add to dashboard Cite

“…Large number of organic derivatives of dialkyl dithiophosphate have been described in the early literature [2][3][4] but the corresponding organic derivatives of alkylene dithiophosphate are still less known [5][6][7][8] .…”

Section: Introductionmentioning

confidence: 99%

p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE

Chordia¹,

Chaturvedi²

2008

J. Chil. Chem. Soc.

View full text Add to dashboard Cite

ABSTRACTp-Nitrophenyl and p-nitrobenzoyl derivatives of O,O'-alkylene dithiophosphate, OGOP(S)SC 6 H 4 NO 2 and OGOP(S)SCOC 6 H 4 NO 2 (Where G = -CMe 2 CMe 2 -, -CH 2 CMe 2 CH 2 -, -CMe 2 CH 2 CHMe-, -CH 2 CH 2 CHMe-) have been synthesized by the reactions of p-bromo nitrobenzene / p-nitrobenzoyl chloride with ammonium salt of alkylene dithiophosphoric acids. These derivatives are yellow and red coloured solids, respectively and are soluble in common organic solvents. These are characterized by elemental analysis, IR and NMR ( 1 H and 31 P) spectral studies. In contrast to the bi-dentate chelating behaviour of the ligand in the metal and organometal derivatives of alkylene dithiophosphates, the behaviour of dithiophosphato moiety in these derivatives is found to be mono-dentate in nature.

show abstract

Synthesis and Properties of 2-Alkylene/Dialkyl Dithiophosphato-2-oxo-1,3,2-dioxaphosphorinanes

Cited by 8 publications

References 16 publications

Synthesis and Properties of N-Bromosuccinimide Derivatives of Ammonium Dialkyl/Alkylene Dithiophosphates

Synthesis and Properties of N-Bromosuccinimide Derivatives of Ammonium Dialkyl/Alkylene Dithiophosphates

Synthetic, spectral as well as in vitro antimicrobial studies on some bismuth(III) bis(N,N‐dialkyldithiocarbamato) alkylenedithiophosphates

p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE

Contact Info

Product

Resources

About