Synthesis and properties of 1-diphenylboryl-2-diphenylphosphino1,2-diphenylethene

Balueva, A. S.; Nikonov, G. N.

doi:10.1007/bf00697092

Cited by 15 publications

(10 citation statements)

References 1 publication

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…[5] Most notably such systems have been used for the heterolytic activation of dihydrogen and concomitantly for metal-free catalytic hydrogenation of several functionalized alkenes [6] and bulky imines. [7][8][9] Frustrated Lewis pairs have been shown to add to olefinic substrates, [10,11] to terminal alkynes, [11,12] to N 2 O, [13] to organic carbonyl compounds [11,14] and even to carbon dioxide. [15] The intramolecular frustrated Lewis pair 1 (Scheme 1) was shown to be especially reactive in some of these binding or activation reactions of small molecules.…”

Section: Dedicated To Professor Günther Wilke On the Occasion Of His mentioning

confidence: 99%

Formation of Cyclic Allenes and Cumulenes by Cooperative Addition of Frustrated Lewis Pairs to Conjugated Enynes and Diynes

et al. 2010

View full text Add to dashboard Cite

Section: Dedicated To Professor Günther Wilke On the Occasion Of His mentioning

confidence: 99%

Formation of Cyclic Allenes and Cumulenes by Cooperative Addition of Frustrated Lewis Pairs to Conjugated Enynes and Diynes

et al. 2010

View full text Add to dashboard Cite

“…Es wurde über eine Reihe von Systemen berichtet, bei denen ein dreiwertiges Phosphorzentrum und ein dreiwertiges Borzentrum durch ungesättigte organische Bausteine miteinander verbunden sind 13. 20c, 24c–e Die photophysikalischen Eigenschaften solcher Verbindungen wurden ausführlich untersucht 79. Einige dieser π‐konjugierten P‐B‐Systeme bilden interne Addukte,80 andere zeigen Reaktionsweisen, die an jene der frustrierten Lewis‐Paare erinnern, z.…”

Section: Anwendungen In Der Metallorganischen Chemieunclassified

How diabetes and insulin therapy affects the lives of people with type 1 diabetes

Nafees

Lloyd

Kennedy-Martin

et al. 2006

European Diabetes Nursing

View full text Add to dashboard Cite

Background: Management of type 1 diabetes places a considerable burden upon patients in terms of frequent insulin injections and blood glucose monitoring. Aims: Patients' fears and thoughts concerning diabetes and treatment were explored in two focus groups. The features of insulin therapy most likely to influence treatment preferences of type 1 patients were investigated. These features would then be used to inform a quantitative patient preference study using a discrete choice experiment. Method: This qualitative study utilised two focus groups, guided by a detailed discussion script based upon clinician input and literature review. Six main topics related to diabetes and insulin therapy were discussed; impact on patient's lifestyle, hypoglycaemic events, predictability and ability to maintain blood glucose levels within recommended targets, injection devices, and negative effects of insulin therapies. In addition, the value people would place on improved insulin therapy measured in terms of their willingness to pay for new therapies, was discussed. Participants were recruited using a screener based upon clinician input. A total of 11 participants attended the two sessions. Transcripts were analysed using content analysis. Results: Participants reported that all six areas were of significant importance in diabetes management. Diabetes and insulin therapy had a huge impact on lifestyle in terms of activity and diet. Fear and experience of hypoglycaemic events were reported as significant concerns. Participants described predicting variation in glucose levels as the key to better management. Participants were willing to pay from £0.70 to £5.00 a day for a better insulin therapy. Conclusion: Diabetes and insulin therapy affects many areas of a patient's life. These data may help understand patients' motivations and treatment preferences, and shape future management and improve diabetic care.Eur Diabetes Nursing 2006; 3(1): 92-97.

show abstract

“…In very weak or non-HB donor solvents such as hexanes, the spectra show a dominant band at ∼370 nm; however, with increasing HB donor strength (dichloromethane < CHCl 3 < MeOH), 14 this absorption band becomes weaker, and the bands between 260 and 350 nm strengthen. In MeOH, the absorption spectrum is similar to that …”

mentioning

confidence: 96%

Tunable Luminescence of Bithiophene-Based Flexible Lewis Pairs

et al. 2015

View full text Add to dashboard Cite

Bithiophene-based flexible Lewis pairs with P(O)R2 (R = phenyl, isopropyl) and BMes2 (Mes = 2,4,6-trimethylphenyl) functionalities are able to toggle between closed, Lewis adduct and open, unbound Lewis pair structures. The open structure is favored in strong hydrogen bond donating solvents or at higher temperatures giving rise to an intense charge-transfer (CT) luminescence, while the closed structure without this emission dominates in non-hydrogen bond donating solvents or at lower temperatures. Intermediate solvents result in an equilibrium mixture of both structures, which shows unusual mixed emission that is dependent on excitation wavelength.

show abstract

Synthesis and properties of 1-diphenylboryl-2-diphenylphosphino1,2-diphenylethene

Cited by 15 publications

References 1 publication

Formation of Cyclic Allenes and Cumulenes by Cooperative Addition of Frustrated Lewis Pairs to Conjugated Enynes and Diynes

Formation of Cyclic Allenes and Cumulenes by Cooperative Addition of Frustrated Lewis Pairs to Conjugated Enynes and Diynes

How diabetes and insulin therapy affects the lives of people with type 1 diabetes

Tunable Luminescence of Bithiophene-Based Flexible Lewis Pairs

Contact Info

Product

Resources

About