Synthesis and physico-chemical properties of a H-cardanol triazole zinc porphyrin conjugate

Rao, H. Surya Prakash; Kamalraj, M.; Prabakaran, M.

doi:10.1039/c8ra09998g

Cited by 8 publications

(2 citation statements)

References 34 publications

(29 reference statements)

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“…In another report, Prakash Rao et al [ 65 ] highlighted the click protocol to accomplish the synthesis of hydrogenated cardanol-triazole-zinc-porphyrin conjugate 160 and triazole-zinc-porphyrin conjugate 162 by the reaction between zinc porphyrin 146 with cardanol azide 159 or 161 , respectively ( Scheme 34 ). Different solvents were used to conduct their UV–vis and fluorescence experiments and the results were compared to other related molecules.…”

Section: Reviewmentioning

confidence: 99%

CuAAC-inspired synthesis of 1,2,3-triazole-bridged porphyrin conjugates: an overview

Singh¹

2023

Beilstein J. Org. Chem.

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Among all the available approaches in organic synthesis, the “click chemistry” protocol is very common nowadays to covalently connect two diverse moieties in a single framework. Therefore, this review focuses on the synthesis and photophysical studies of β- and meso-substituted and 1,2,3-triazole-fused porphyrin conjugates. All of the porphyrin conjugates discussed here are synthesized via a copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition reaction between an azide and a terminal alkyne, also popular as "click reaction" or CuAAC reaction. Moreover, the 1,2,3-triazole ring also serves as a spacer and an electron transfer bridge between the porphyrin and the attached chromophores. In order to provide a critical overview of the synthesis and properties of various porphyrin-triazole hybrids, this review will discuss some of the key reactions involved in the preparation of triazole-linked porphyrin conjugates.

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Section: Reviewmentioning

confidence: 99%

CuAAC-inspired synthesis of 1,2,3-triazole-bridged porphyrin conjugates: an overview

Singh¹

2023

Beilstein J. Org. Chem.

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“…More recently, Prabakaran and co-workers reported the synthesis of porphyrin derivative P31 bearing four H-cardanol units (Figure 3), a waste by-product of the cashew industry, linked by triazolyl bridges prepared via a CuAAC reaction [34]. J-type aggregates formation is induced when compound P31 was studied in polar protic and aprotic solvents, due to the long alkyl chains of the H-cardanol moieties.…”

Section: Scheme 1 Schematic Preparation Of Microporous Porphyrin-basmentioning

confidence: 99%

Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 1—Azides, Porphyrins and Corroles

et al. 2020

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Azides and porphyrinoids (such as porphyrin and corrole macrocycles) can give rise to new derivatives with significant biological properties and as new materials’ components. Significant synthetic approaches have been studied. A wide range of products (e.g., microporous organic networks, rotaxane and dendritic motifs, dendrimers as liquid crystals, as blood substitutes for transfusions and many others) can now be available and used for several medicinal and industrial purposes.

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Cationic Zn-Porphyrin Polymer Coated on CNTs as Bifunctional Catalyst for the Conversion of CO2 to Cyclic Carbonates

et al. 2021

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Synthesis and physico-chemical properties of a H-cardanol triazole zinc porphyrin conjugate

Abstract: A fluorescent and fat-soluble zinc porphyrin incorporating four units of hydrogenated cardanol (H-cardanol) was synthesized, and its physico-chemical properties were characterized.

Cited by 8 publications

References 34 publications

CuAAC-inspired synthesis of 1,2,3-triazole-bridged porphyrin conjugates: an overview

CuAAC-inspired synthesis of 1,2,3-triazole-bridged porphyrin conjugates: an overview

Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 1—Azides, Porphyrins and Corroles

Cationic Zn-Porphyrin Polymer Coated on CNTs as Bifunctional Catalyst for the Conversion of CO2 to Cyclic Carbonates

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