Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II)

Synthesis, Characterization, and Antitumor Activity of New Organotin(IV) Methoxyethyldithiocarbamate Complexes

“…Dithiocarbamates deal with a great interest in inorganic synthesis as they have a number of applications. These ligands have attracted the attention among scientists because of their potential biological activities (Leka et al 2006). Their metal complexes present striking structural features and have diversified applications such as high-pressure lubricants and accelerators used in vulcanization (Beer et al 2001).…”

Thermal Analysis of Sulfur and Selenium Compounds with Multiple Applications, Including Anticancer Drugs

“…Coordination compounds with dithiocarbamates have attracted attention because of their potential biological activity [7][8][9][10]. In 2006, a novel dithiocarbamate ligand L (triammonium-N-dithiocarboxyiminodiacetate) was synthesized and the thermal decomposition of its cooper (II), niquel (II) and palladium (II) was studied by DSC and thermogravimetry [11]. The authors showed that thermal stability of (NH4)3L is low and its decomposition starts with evaporation of an ammonia molecule.…”

“…It is endothermic up to 500 K, but exothermic oxidation processes are observed above this temperature. Thermal decomposition of the cooper (II) complex is accompanied by its melting and with an exothermic structural rearrangement [11]. During the last two years, these thermal techniques have been used to study the stability and to characterize the degradation process of several dithiocarbamate complexes [12][13][14].…”

“…The thermal behaviour of Pd(II) complexes with some dithiocarbamate derivatives was studied in order to establish the coordination mode of the ligand, to test the thermal stability [11] or to understand the effect of the alkyl chain attached to the nitrogen atom over the thermochemical parameters of the complexes [74,75]. A series of Pd(II) complexes with tertbutylsarcosinedithiocarbamate [76], ethylsarcosinedithiocarbamate and 2-/3-picoline [77], dithiocarbamates and various amines [78] were developed as antitumor agents with low nephrotoxicity.…”

Antibacterial Application of Novel Mixed-Ligand Dithiocarbamate Complexes of Nickel (II)

“…An extremely large number of dithiocarbamate complexes with transition and non transition metal ions have been reported (Dawood et al2009; Daniel et al2009 andSarwar et al2007). Compounds with dithiocarbamate moiety have attracted attention because of their potential biological activity (Leka et al 2006). Their metal complexes present striking structural features and have diversified applications, such as high pressure lubricants, fungicides, pesticides, and accelerators used in vulcanization (Beer et al2001).…”