Synthesis and photovoltaic characterization of D/A structure compound based on N-substituted phenothiazine and benzothiadiazole

Yun, Dae-Hee; Yoo, Han-Sol; Heo, Seok; Song, Ho-Jun; Moon, Doo-Kyung; Woo, Je-Wan; Park, Yong-Sung

doi:10.1016/j.jiec.2012.08.033

Cited by 27 publications

(10 citation statements)

References 45 publications

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“…Furthermore, the application of small organic compounds in optoelectronics is an emerging area that has been extensively investigated as this could lead to the development of more flexible and lower cost smaller devices e.g. solar cells, OLEDs, OFETs, OTFTs [31][32][33][34]. In this regard, heteroaromatic small molecules and hybrid compounds also have been largely investigated [35].…”

Section: Introductionmentioning

confidence: 99%

Selenylated-oxadiazoles as promising DNA intercalators: Synthesis, electronic structure, DNA interaction and cleavage

et al. 2020

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Elsevier has created a COVID-19 resource centre with free information in English and Mandarin on the novel coronavirus COVID-19. The COVID-19 resource centre is hosted on Elsevier Connect, the company's public news and information website. Elsevier hereby grants permission to make all its COVID-19-related research that is available on the COVID-19 resource centre-including this research content-immediately available in PubMed Central and other publicly funded repositories, such as the WHO COVID database with rights for unrestricted research re-use and analyses in any form or by any means with acknowledgement of the original source. These permissions are granted for free by Elsevier for as long as the COVID-19 resource centre remains active.

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Section: Introductionmentioning

confidence: 99%

Selenylated-oxadiazoles as promising DNA intercalators: Synthesis, electronic structure, DNA interaction and cleavage

et al. 2020

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“…After the reaction is completed, if filtered for NaOH removal and extraction is performed with EA. (Washing with distilled water and brine) MgSO4 is used for drying, then, after removing the solvent, purification is performed with column chromatography [21][22][23][24] …”

Section: -(Alkyl)-10h-phenothiazinementioning

confidence: 99%

“…The collected organic layer dried with MgSO4 and the solvent was removed through vacuum evaporation. Then, purified by using column chromatography to obtain the product [22,25,26] 2.4.4. 10-(Alkyl)-3,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaboraolan-2-yl)-10H-phenothiazine (M1a-c) In a 2-neck flask, 6 mmol of 3,7-dibromo-10-(alkyl)-10H-phenothiazine is completely dissolved in 50 mL THF and stirred at -78 ℃ under nitrogen.…”

Section: 7-dibromo-10-(alkyl)-10h-phenothiazinementioning

confidence: 99%

“…The mixture was poured into water, extracted with ether, and dried with MgSO4. The crude product was purified by recrystallization with ethanol [22,26,27 2.4.6. 1,2-Dinitro-4,5-bis(octyloxy)benzene In 1000 mL 3-neck flask, 62.77 mmol of 1,2-dioctlyoxybenzene and 90 mL of acetic acid was dissolved 90 mL of MC and stirred at 0 ℃ for 1 h under nitrogen atmosphere.…”

Section: 7-dibromo-10-(alkyl)-10h-phenothiazinementioning

confidence: 99%

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Synthesis, Photovoltaic Properties and Side-chain Effect of Copolymer Containing Phenothiazine and 2,1,3-Benzothiadiazole

Yun¹,

Yoo²,

Seong³

et al. 2014

Applied Chemistry for Engineering

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In this study, three kinds of polymers based on phenothiazine-benzothiadiazole were synthesized by a Suzuki coupling reaction, and the various side-chains were substituted at the nitrogen of phenothiazine. The optical and electrochemical properties of synthesized polymers were analyzed. The results indicate that their absorption ranged from 300 to 700 nm, and also confirmed the ideal highest occupied molecular orbital (HOMO) energy level was about -5.4 eV with low band-gap energy. Photovoltaic devices were fabricated using a photoactive layer composed of a blended solution of the polymer and PC71BM in ortho-dichlorobenzene The device with P2HDPZ-bTP-OBT containing the branched side-chain and long chain showed the best performance; the maximum power conversion efficiency of this device was 2.4% (with VOC : 0.74 V, JSC : 6.9 mA/cm 2 , FF : 48.0%).

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“…In recent years the 2,1,3-benzothiadiazole (BTD) as a good acceptor unit installed in the multimodular D-A systems has gained significant attention due to its several advantages such as favorable reduction potential, a prominent bathochromic shift of the charge transfer absorption band, and strong electron affinity. The BTD derivatives have widely been used as π-conjugated organic materials for two-photon absorption, photoinduced intramolecular charge transfer (ICT), organic light-emitting diodes (OLED), and solar cells [4,[22][23][24][25][26][27][28][29]. The nature of the donor and of the acceptor and the geometry of the linker between them are important factors that affect the properties of such compounds.…”

Section: Introductionmentioning

confidence: 99%

New Unsymmetrically Substituted Benzothiadiazole-Based Luminophores: Synthesis, Optical, Electrochemical Studies, Charge Transport, and Electroluminescent Characteristics

et al. 2021

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Three new benzothiadiazole (BTD)-containing luminophores with different configurations of aryl linkers have been prepared via Pd-catalyzed cross-coupling Suzuki and Buchwald–Hartwig reactions. Photophysical and electroluminescent properties of the compounds were investigated to estimate their potential for optoelectronic applications. All synthesized structures have sufficiently high quantum yields in film. The BTD with aryl bridged carbazole unit demonstrated the highest electrons and holes mobility in a series. OLED with light-emitting layer (EML) based on this compound exhibited the highest brightness, as well as current and luminous efficiency. The synthesized compounds are not only luminophores with a high photoluminescence quantum yield, but also active transport centers for charge carriers in EML of OLED devices.

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Synthesis and photovoltaic characterization of D/A structure compound based on N-substituted phenothiazine and benzothiadiazole

Cited by 27 publications

References 45 publications

Selenylated-oxadiazoles as promising DNA intercalators: Synthesis, electronic structure, DNA interaction and cleavage

Selenylated-oxadiazoles as promising DNA intercalators: Synthesis, electronic structure, DNA interaction and cleavage

Synthesis, Photovoltaic Properties and Side-chain Effect of Copolymer Containing Phenothiazine and 2,1,3-Benzothiadiazole

New Unsymmetrically Substituted Benzothiadiazole-Based Luminophores: Synthesis, Optical, Electrochemical Studies, Charge Transport, and Electroluminescent Characteristics

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