“…Not surprisingly, fluorides as well as their doped analogues have found wide applicability as components of high-density optical devices, lenses, biological labels, sensors, and insulators. [18][19][20] What is less known is that ternary metal fluorides, possessing cubic perovskite structures with a chemical formula of AMnF 3 (A = K, NH 4 , Rb, Tl, Cs), are antiferromagnetic and that these materials have generated considerable interest due to their exceptional magnetic, piezoelectric, and photoluminescent properties. [21][22][23][24] In fact, this family of cubic perovskites provides an excellent example of simple cubic Heisenberg antiferromagnets with spin S = 5/2.…”