Synthesis and Nonlinear Optical Properties of Novel Y-Type Polyurethane Containing Cyanovinylthiazole

No, Hyo Jin; Cho, You Jin; Lee, Ju‐Yeon

doi:10.1080/15421400903584382

Cited by 1 publication

(1 citation statement)

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“…More recently, Petroff et al used the same strategy and created polar molecules doped polydimethylsiloxane (PDMS) foams and measured the electrical and mechanical properties and by tuning these properties they achieved a maximum d 33 piezo-coefficients about 153 pCN −1 [4]. Furthermore, many researchers showed that the inclusion of polar molecules in polyurethane can create either high piezoelectricity or NLO materials [27][28][29][30][31][32][33][34][35][36][37][38][39][40][41]. We motivated by reviewing the previous works to do further experiments to observe the effect of polar moieties on other properties of polyurethane.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of cross-linked polyurethane elastomers with the inclusion of polar-aromatic moieties (BA, PNBA and 3, 5-DNBA): Electrical and thermo-mechanical properties analysis

2021

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In this work, we used the design strategy “doped nonpolar polymers” and synthesized the polyurethane elastomers (PUEs) by doping with highly polar aromatic molecules such as benzoic acid (BA), 4(para)-nitro-benzoic acid (PNBA), and 3, 5-di-nitro-benzoic acid (3, 5-DNBA) by using the solution casting method. The effect of each molecule in three different weight percentages 2%, 4%, and 6% on electrical and thermo-mechanical properties of the material has studied. Experiments were carried out to determine electrical properties such as DC volume resistivity, dielectric constant, and loss factor. DMA and DSC measurements were done to assess thermo-mechanical properties. Also, thermal conductivity measurement was carried out and a strong nitro group and doping percentage dependent results have been observed. A comparative analysis of the effect on the said properties was done among the doped and undoped PUEs.

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