1992
DOI: 10.1021/ic00034a007
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Synthesis and molecular structure of an iminophosphide/phosphinoamide anion: [Li(PhN-PPh2)(OEt2)]2

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Cited by 54 publications
(74 citation statements)
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“…Upon NR] 2 or P 4 N 6 R 6 , we did not include a study of the deprolithiation, amidophosphanes RLiNϪPR 2 form. [2] Associtonation of tris(amino)phosphanes. ation of these molecules should preferentially occur by means of intermolecular Li···N interactions, although Li···P interactions may also be present; [2] these should, however, Results not be preferential due to the softer base character of the phosphorus(III) atom.…”
Section: Introductionmentioning
confidence: 99%
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“…Upon NR] 2 or P 4 N 6 R 6 , we did not include a study of the deprolithiation, amidophosphanes RLiNϪPR 2 form. [2] Associtonation of tris(amino)phosphanes. ation of these molecules should preferentially occur by means of intermolecular Li···N interactions, although Li···P interactions may also be present; [2] these should, however, Results not be preferential due to the softer base character of the phosphorus(III) atom.…”
Section: Introductionmentioning
confidence: 99%
“…[2] Associtonation of tris(amino)phosphanes. ation of these molecules should preferentially occur by means of intermolecular Li···N interactions, although Li···P interactions may also be present; [2] these should, however, Results not be preferential due to the softer base character of the phosphorus(III) atom. Moreover, it is well-known that ami-Bis(organoamino)organophosphanes, RЈP(NHR) 2 nophosphanes may be involved in prototropism (A) which can lead to imido-phosphoranes; [3] metallotropism, as deAminophosphanes RЈ 3Ϫn P(NHR) n bearing primary amino groups are amenable to condensation.…”
Section: Introductionmentioning
confidence: 99%
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