Synthesis and Modular Reactivity of Low Valent Al/Zn Heterobimetallics Supported by Common Monodentate Amides
Fabian Dankert,
Eva Hevia
Abstract:Recent advances on low valent main group metal chemistry have shown the excellent potential of heterobimetallic complexes derived from Al(I) to promote cooperative small molecule activation processes. A signature feature of these complexes is the use of bulky chelating ligands which act as spectators providing kinetic stabilization to their highly reactive Al‐M bonds. Breaking new ground in this field, here we report the synthesis of novel unsupported Al/Zn bimetallics prepared by the selective formal insertio… Show more
Reaction of neutral olefin complexes of ruthenium and molybdenum with GaTMP (TMP = 2,2,6,6-tetramethylpiperidinyl) by substitution leads to the formation of respective five and six coordinated homoleptic products. [Ru(GaTMP)5] (1)...
Reaction of neutral olefin complexes of ruthenium and molybdenum with GaTMP (TMP = 2,2,6,6-tetramethylpiperidinyl) by substitution leads to the formation of respective five and six coordinated homoleptic products. [Ru(GaTMP)5] (1)...
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