Synthesis and Mesogenic Properties of Liquid Crystals Containing Terminal Cyclohexylmethanol, Cyclopentylmethanol, Cyclobutylmethanol and Cyclopropylmethanol Moiety

Abstract

Four series of compounds 11~50 containing terminal alicyclic rings such as cyclohexylmethyl, cyclopentylmethyl, cyclobutylmethyl, and cyclopropylmethyl rings were synthesized and their liquid crystal behavior studied. The ring size and the length of flexible alkoxy chain influence the phase formation in different ways. While the smaller ring and the shorter alkoxy chain tend to favor the formation of the N phase, the larger ring and the longer alkoxy chain tend to favor the formation of the SmC phase. All the compounds except 11 and 21 exhibit SmA phases. The widest temperature range of the N, SmA, and SmC phases are found in the compounds 41, 46, and 20, respectively, which are 75 o C for 41, 115 o C for 46, and 100 o C for 20.