Synthesis and luminescence properties of a bluish-green emitting phosphor Ba3(PO4)2: Ce3+, Tb3+

Tong, Miaohui; Liang, Yujun; Peng, Yan; Wang, Qiang

doi:10.1016/j.optlastec.2015.07.007

Cited by 17 publications

(5 citation statements)

References 49 publications

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“…Moreover, mazorite was also detected in a carbonate–silicate xenolith from the Bellerberg volcano area in Germany, where it occurs as a small inclusion (<15 μm) inside the bennesherite crystal (Juroszek and Ternes, 2022). Synthetic mazorite doped with various metals and rare earth elements is an important phosphor material characterised by colour purity and good luminescence efficiency (Tāle et al , 1979; Mu and He, 2012; Tong et al , 2015).…”

Section: Background Information Of the Palmierite-supergroup Membersmentioning

confidence: 99%

“…Moreover, this type of structure is also noted for materials with the formula A 5 R(MoO 4 ) 4 (A + = K, Rb and Tl; R 3+ = REE, Y, Bi, Fe and In) (Tsyrenova et al, 2016). Currently, the inorganic crystal structure database (ICSD, https://icsd.products.fiz-karlsruhe.de/) lists ∼100 compounds with the same structure type and, depending on the chemical composition, these palmierite-type materials exhibit various optical, luminescence, ferroelectric and catalytic properties (Lagos, 1970;Grzechnik and McMillan, 1997;Mugavero et al, 2008;Thompson et al, 2013;Tong et al, 2015). Some compounds, due to the crystal structure flexibility, can accommodate large ion lithophile elements (LILE) and different luminescent ions, mainly rare-earth elements (REE) (Lagos, 1970;Murayama et al, 1986;Sugiyama and Tokonami, 1987;Xie et al, 2004;Thompson et al, 2013;Cao et al, 2014;Tong et al, 2015).…”

Section: Introductionmentioning

confidence: 99%

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Minerals with a palmierite-type structure. Part II. Nomenclature and classification of the palmierite supergroup.

Juroszek

Krüger

et al. 2023

MinMag

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The palmierite supergroup, approved by the IMA-CNMNC, includes five mineral species characterised by the general crystal-chemical formula XIIM1XM22(IVTO4)2 (Z = 3). On the basis of the crystal-chemical arguments and heterovalent isomorphic substitution scheme M++T6+ ↔ M2++T5+, the palmierite supergroup can be formally divided into two groups: the palmierite group M12+M22+(T6+O4)2, and the tuite group M12+M222+(T5+O4)2. Currently, the palmierite group includes palmierite K2Pb(SO4)2, and kalistrontite K2Sr(SO4)2, whereas the tuite group combines tuite Ca3(PO4)2, mazorite Ba3(PO4)2, and gurimite Ba3(VO4)2. The isostructural supergroup members crystallise in space group R $\bar{3}$ m (no. 166). The palmierite-type crystal structure is characterised by a sheet arrangement composed of layers formed by M1O12 and M2O10 polyhedra separated by TO4 tetrahedra perpendicular to the c axis. The abundance of distinct ions, which may be hosted at the M and T sites (M = K, Na, Ca, Sr, Ba, Sr, Pb, Rb, Zn, Tl, Cs, Bi, NH4 and REE; T = Si, P, V, As, S, Se, Mo, Cr and W) implies many possible combinations, resulting in potentially new mineral species. Minerals belonging to the palmierite supergroup are relatively rare and usually form under specific conditions, and their synthetic counterparts play a significant role in various industrial applications.

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Section: Background Information Of the Palmierite-supergroup Membersmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Minerals with a palmierite-type structure. Part II. Nomenclature and classification of the palmierite supergroup.

Juroszek

Krüger

et al. 2023

MinMag

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“…In materials science, Ba 3 (PO 4 ) 2 is an important phosphor material characterised by good luminescence efficiency and colour purity. The crystal structure is quite flexible and can accommodate different luminescent ions, such as rare-earth elements (Tāle et al , 1979; Mu and He, 2012; Tong et al , 2015). Previous publications show that barium orthophosphate is a host material characterised by the ability to form visible-emitting phosphors doped with metal and rare-earth ions e.g.…”

Section: Introductionmentioning

confidence: 99%

“…Previous publications show that barium orthophosphate is a host material characterised by the ability to form visible-emitting phosphors doped with metal and rare-earth ions e.g. Ni 2+ , Mn 2+ , 3+ , 5+ , Ce 3+ , Eu 2+ , 3+ , Yb 2+ , Sm 3+ and Tb 3+ (Lagos, 1970; Tāle et al , 1979; Cao et al , 2014; Tong et al , 2015). Furthermore, a novel magnetic absorbent (BPF), a composite of Ba 3 (PO 4 ) 2 nanoflakes and Fe 3 O 4 microspheres, could be an interesting material for removing organic dyes, like methyl blue, from polluted water, due to their good absorption and easy magnetic separation abilities (Zhang et al , 2016).…”

Section: Introductionmentioning

confidence: 99%

Minerals with a palmierite-type structure. Part I. Mazorite Ba₃(PO₄)₂, a new mineral from the Hatrurim Complex in Israel

Juroszek,

Galuskina,

Krüger

et al. 2023

MinMag

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The new mineral mazorite, ideally Ba3(PO4)2, a P-analogue of gurimite Ba3(VO4)2, was discovered in rankinite paralava hosted by the massive gehlenite-bearing pyrometamorphic rocks of the Hatrurim Complex in Israel. It has also recently been discovered in xenolith samples from the Bellerberg volcano in Germany. Holotype mazorite usually forms colourless plate-like crystals up to 70–100 μm in length but also occurs in small aggregates in association with other rare Ba-bearing minerals such as zadovite, celsian, hexacelsian, bennesherite, sanbornite, walstromite, fresnoite, gurimite, alforsite and barioferrite. The mineral is transparent, exhibits vitreous lustre and has a good cleavage on (001). Optically, mazorite is uniaxial (+), with ω = 1.760(3) and ɛ = 1.766(3) (λ = 589 nm). The empirical formula of the holotype mazorite calculated on 8O is (Ba2.69K0.22Na0.04Ca0.02Sr0.01)Σ2.98(P1.16V0.57S0.24Al0.04Si0.03)Σ2.04O8. Mazorite crystallises in space group R $\bar{3}$ m, with unit-cell parameters a = 5.6617(5) Å, c = 21.1696(17) Å, V = 587.68(9) Å3 and Z = 3. Its crystal structure consists of BaO12, BaO10, and PO4 polyhedra, ordered along the c-axis in PO4–BaO10–BaO12–BaO10–PO4 columnar arrangement characteristic for palmierite-supergroup minerals. A tetrahedrally coordinated site is generally occupied by P5+ but can be partially substituted by V5+ and S6+. This substitution is shown in the Raman spectrum of mazorite, which reveals bands that can be assigned to the stretching and bending vibrations of (PO4)3–, (VO4)3– and (SO4)2– groups. The Raman spectra of mazorite from two localities (Hatrurim and Bellerberg) and spectra of minerals belonging to the mazorite Ba3(PO4)2 to gurimite Ba3(VO4)2 solid-solution series are presented. The gradual shift of the Raman bands, caused by cation substitutions, is well observed. The high V5+ → P5+ substitution is also observed for gurimite, for which the first X-ray structural data are also presented. Mazorite and other Ba-bearing minerals crystallised from a small portion of residual melt enriched in incompatible elements, such as Ba, V, P, U, S, Ti and Nb, at a temperature of ~1000°C.

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“…Other materials, such as tungsten phosphate and rare earth oxides, can be easily synthesized, however they are chemically instable . Barium pyrophosphate is a promising host for luminescent materials due to its low sintering temperature and stability …”

Section: Introductionmentioning

confidence: 99%

Luminescent properties of single‐phase Ba_{2‐x‐1.5y‐1.5z}P₂O₇:xEu²⁺,yCe³⁺, zTb³⁺ phosphors for white light‐emitting diode

et al. 2017

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Abstractpoor color rendering index and low stability of CCT. [1,4] Given that issue, it is necessary to explore single-phase white emissive phosphors for application in w-LEDs.Numerous efforts have previously been made to develop codoped single-phase white-emitting phosphors. [5,6] However, with the tri-doped phosphor it is easier to achieve tri-chromatic (RGB) emission with complete coverage when compared with co-doped phosphors. It is well known that the mixture of RGB emissions is more beneficial to generate an ideal warm white-light emission according to trichromatic theory. [7] Hence, more researchers have devoted themselves to developing the more complex tri-doped single-phase white-emitting phosphors. For example, Jiang and colleagues [8] It is a known reality that most phosphors are prepared via a conventional solid-state route, which has unavoidable disadvantages such as high synthesis temperature, nonhomogeneous mixtures and uncontrollable morphology. In particular, the obtained particles are very large with sizes in the range 1-10 μm. [9,10] In recent years, more researchers have focused on the co-precipitation method, which can overcome the above disadvantages and obtain nanophosphors with excellent luminescence properties. [9][10][11][12][13][14] Among these, Yi and colleagues [15] short, the co-precipitation method is very safe, energy-saving, timesaving option.At present, the most common hosts are aluminate and silicate systems with high stability and high QE. [16] But their synthesis conditions are harsh, in particular the synthesis temperatures are often as high as 1300°C. [17] Other materials, such as tungsten phosphate and rare earth oxides, can be easily synthesized, however they are chemically instable.[18] Barium pyrophosphate is a promising host for luminescent materials due to its low sintering temperature and stability. [18][19][20] Among the trivalent rare earth ions, Tb 3+ ion has been used frequently as the green emission center owing to its predominant 5 D 4 ! 7 F 5 transition with a peak centered at 545 nm. However, because of the forbidden transition and the weak absorption of Tb 3+ ion in the NUV region, the emission efficiency is low. [20,21] As is well known, Ce 3+ and Eu 2+ are often considered as the most important activator and effective sensitizer for Tb 3+ because of their unique electronic energy levels. [22][23][24][25] To the best of our knowledge, the crystal structures and lumines- | CharacterizationThe crystal phase of phosphor sample was analyzed by a SHIMADZU XRD-6000 diffractometer (Shimadzu Co., Japan) with Ni-filtered Cu single-phase. Ba 2 P 2 O 7 crystallized as a hexagonal structure with a space group p-62m and the lattice parameters were determined to be a = b = 9.415Å, c = 7.078Å, the crystal structure diagram of which is presented in Figure 2(a). The hexagonal form of Ba 2 P 2 O 7 signified that the sample host was at a higher temperature phase as σ-Ba 2 P 2 O 7 .Ba ions have two different types of coordination environments, in which one is coordinated b...

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Synthesis and luminescence properties of a bluish-green emitting phosphor Ba3(PO4)2: Ce3+, Tb3+

Cited by 17 publications

References 49 publications

Minerals with a palmierite-type structure. Part II. Nomenclature and classification of the palmierite supergroup.

Minerals with a palmierite-type structure. Part II. Nomenclature and classification of the palmierite supergroup.

Minerals with a palmierite-type structure. Part I. Mazorite Ba₃(PO₄)₂, a new mineral from the Hatrurim Complex in Israel

Luminescent properties of single‐phase Ba_{2‐x‐1.5y‐1.5z}P₂O₇:xEu²⁺,yCe³⁺, zTb³⁺ phosphors for white light‐emitting diode

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Synthesis and luminescence properties of a bluish-green emitting phosphor Ba3(PO4)2: Ce3+, Tb3+

Cited by 17 publications

References 49 publications

Minerals with a palmierite-type structure. Part II. Nomenclature and classification of the palmierite supergroup.

Minerals with a palmierite-type structure. Part II. Nomenclature and classification of the palmierite supergroup.

Minerals with a palmierite-type structure. Part I. Mazorite Ba3(PO4)2, a new mineral from the Hatrurim Complex in Israel

Luminescent properties of single‐phase Ba2‐x‐1.5y‐1.5zP2O7:xEu2+,yCe3+, zTb3+ phosphors for white light‐emitting diode

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Product

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Minerals with a palmierite-type structure. Part I. Mazorite Ba₃(PO₄)₂, a new mineral from the Hatrurim Complex in Israel

Luminescent properties of single‐phase Ba_{2‐x‐1.5y‐1.5z}P₂O₇:xEu²⁺,yCe³⁺, zTb³⁺ phosphors for white light‐emitting diode