Synthesis and interpolymer complexation of a novel polycation with 2-hydroxyl-3-ethoxyprop-1-yl groups, high density of charge and excellent proton buffering capability

Wu, Chuanbao; Hao, Jian; Liu, Li-Jiang; Xianghui, Zeng

doi:10.1007/s00289-022-04180-8

Cited by 1 publication

(1 citation statement)

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“…This can be related to hydrogen atom 3 as labeled in Figure S8. Due to the disappearance of the alkene group, a lower shift for hydrogen atom 3 is expected. , Our hypothesis is substantiated by the emergence of a split peak at 3.7 ppm in the spectra, where a new peak coincides with the previously sharp split peaks. Peaks normally expected from the epoxy group are not visible in the spectra due to overlap with the large DMSO peak; thus, no ring-opening products were quantified.…”

Section: Resultsmentioning

confidence: 99%

Liquid–Liquid-Printed Graphitic Carbon Nitride-Embedded Porous Poly(ionic liquid) Beads as Highly Active Reusable Heterogenous Photocatalysts

Meijer,

Bazyar,

Kumru

2024

ACS Appl. Eng. Mater.

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In this study, we report the synthesis of photocatalytically active composite beads by incorporating graphitic carbon nitride (g-CN) into a poly(ionic liquid) (PIL) matrix. Characterization of these composite beads revealed a highly porous surface structure, with g-CN uniformly embedded throughout the matrix. We assessed the photocatalytic performance of these beads using a thiol−ene click reaction, photocatalytic dye degradation, and hydrogen evolution reactions. Our findings clearly demonstrate the significant enhancement in photocatalytic activity attributable to the poly(ionic ligand) matrix, surpassing the performance of nonionic polymer matrices. This work highlights the potential of g-CN/PIL composite beads as reusable efficient photocatalytic materials for diverse applications such as hydrogen evolution, dye degradation, and selective organic reactions.

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Section: Resultsmentioning

confidence: 99%