Synthesis and electrorheological characteristics of polyaniline-titanium dioxide hybrid suspension

Lee, I.S.; Lee, J.Y.; Sung, Jang Hyun; Choi, Hyoung Jin

doi:10.1016/j.synthmet.2005.07.211

Cited by 73 publications

(29 citation statements)

References 24 publications

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“…Different CP-TiO 2 composite materials have been prepared both by chemical [13][14][15] and electrochemical [16][17][18][19][20][21] means. These composite materials have been synthesized for different applications: electrochemical actuators [17], corrosion protection [18] and PV cells [13,19,21].…”

Section: Introductionmentioning

confidence: 99%

Electrochemical polymerization and characterization of a poly(azulene)-TiO2 nanoparticle composite film

et al. 2008

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A poly(azulene)-TiO 2 composite film (PAz-TiO 2 ) was synthesized electrochemically by oxidation of azulene in an electrolyte medium containing TiO 2 nanoparticles. Polymerization was performed under magnetic stirring in an acetonitrile solution containing tetrabutylammonium hexafluorophosphate as the electrolyte salt. Influence of the concentration of TiO 2 in the reaction suspension on the electrochemical and optical properties and on the structure of the composite films was studied by cyclic voltammetry, ex situ Raman and FTIR reflection spectroscopy and in situ UV-vis and FTIR spectroelectrochemical techniques. Morphology of the composite films was studied by Scanning Electron Microscopy and the amount and distribution of the TiO 2 nanoparticles within the polymeric matrix by Inductively Coupled Plasma Mass Spectrometry with laser ablation. Addition of TiO 2 in the reaction suspension had a small catalytic activity for the polymerization of Az. Inclusion of TiO 2 nanoparticles in PAz did not affect the voltammetric behavior or the chemical structure of the formed polymer films. However, a different chain conformation and morphology of the film was formed when synthesized in presence of TiO 2 compared to the plain PAz film. It was also found that the film morphology was more homogeneous when the concentration of TiO 2 was C10 mM in the polymerization solution than films polymerized without any TiO 2 .

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Section: Introductionmentioning

confidence: 99%

Electrochemical polymerization and characterization of a poly(azulene)-TiO2 nanoparticle composite film

et al. 2008

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“…Among the various electro-responsive ER materials available, conducting polymer/inorganic composites have attracted considerable attention because of their heterogeneous physical properties and unique structure that combine the merits of the two phases [15,16]. Conducting polymers have promising applications in electrochemical devices, photodiodes, antistatic and anticorrosion coatings, batteries, sensors, and solar cells [17,18].…”

Section: Introductionmentioning

confidence: 99%

Fabrication of electric-stimuli responsive polyaniline/laponite composite and its viscoelastic and dielectric characteristics

Jun

Sim

Choi

2015

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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“…Among these oxides, TiO 2 has received particular attention due to its good stability, environmental friendliness, and interesting semiconducting property. Various PANi-TiO 2 nanocomposites have been prepared by using chemical polymerization or electrochemical polymerization of aniline in the presence of TiO 2 nanocolloidals, and have found applications in electrochromic devices [11], p-n heterojunction diodes [12], rectifier [13], gas sensor [14], high piezoresistivity [15], electrorheological response [16], cathode electrode in rechargeable battery [17], and photoelectrochemical devices [5,6,11,18]. PANi-TiO 2 nanocomposites were usually prepared in the form of thin film, powder, sphere [19,20], or tube [21].…”

Section: Introductionmentioning

confidence: 99%

Camphor Sulfonic Acid Doped Polyaniline-Titanium Dioxide Nanocomposite: Synthesis, Structural, Morphological, and Electrical Properties

Pawar¹,

Patil²,

Chougule³

et al. 2011

International Journal of Polymeric Materials

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A nanocomposite of polyaniline-titanium dioxide (PANi-TiO 2 , 50 wt%) was doped with camphor sulfonic acid (CSA) by solid state reaction with increasing CSA content up to 50 wt% in a smooth agate mortar. CSA doped PANi-TiO 2 was dissolved in m-cresol and films were cast using a spin-coating technique. The doping effect of CSA on PANi-TiO 2 nanocomposite was characterized and evaluated by X-ray diffraction pattern (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and electrical conductivity measurement. The XRD spectra showed that the addition of CSA has no effect on crystallinity of PANi-TiO 2 . SEM studies revealed that CSA has a strong effect on morphology of PANi-TiO 2 . The FTIR spectra revealed the interaction between CSA and PANi-TiO 2 nanocomposite. Electrical conductivity measurements indicated that with the increasing content of CSA, the conductivity shows an orderly increase.

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Synthesis and electrorheological characteristics of polyaniline-titanium dioxide hybrid suspension

Cited by 73 publications

References 24 publications

Electrochemical polymerization and characterization of a poly(azulene)-TiO2 nanoparticle composite film

Electrochemical polymerization and characterization of a poly(azulene)-TiO2 nanoparticle composite film

Fabrication of electric-stimuli responsive polyaniline/laponite composite and its viscoelastic and dielectric characteristics

Camphor Sulfonic Acid Doped Polyaniline-Titanium Dioxide Nanocomposite: Synthesis, Structural, Morphological, and Electrical Properties

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