Synthesis and electrochemistry of [{Mo(NO)[HB(3,5-Me2C3HN2)3]Cl}2{1,2-(NH)2C6H4}] and the crystal structure of [{Mo(NO)[HB(3,5-Me2C3HN2)3]I}2{1,2-(NH)2C6H4}]

Coordination and Organometallic Chemistry of Metal−NO Complexes

“…The trends in reduction potentials of a number of similar complexes have also been determined . These include complexes containing Tp*Mo(NO)Cl groups linked by saturated-α,ω-diamido bridging ligands , for some of which the first reductions occur at increasingly anodic potentials as the size of the bridging ligand is decreased. They also include Tp*M(NO)Cl(NHC 6 H 4 -3-Z) (M = Mo, W) systems whose first reduction potentials correlate linearly with the Hammett meta substituent parameters for Z .…”

Mixed-valence dinuclear molybdenum complexes with benzenediamido and dianilido bridges: comparison with related phenolato and dipyridyl species, and with their pentammineruthenium analogues

“…Such a situation can be expected in compounds containing benzenediamido bridges, e.g. in [{Mo(NO)[HB(dmpz) 3 ]X} 2 {(HN) 2 C 6 H 4 }] II (Z = NH, X = halide), 8,9, 13 where the separation between the metal-based redox centres may be varied by choice of the geometric isomers of the [(HN) 2 C 6 H 4 ] 2Ϫ bridge. The effect of the substitution pattern in aromatic bridges on the spectral properties of mixed-valence dinuclear complexes has received sparse attention.…”