Synthesis and electrochemical properties of the N-isocyanurate derivative of azahomo[60]fullerene

Ultrasound‐assisted Cycloadditions of [70]Fullerene with Various 2‐Azidoethyl per‐O‐acetyl Glycosides

“…Thus, the closed [5,6] monoadducts may be formed by ultrasonic irradiation. This phenomenon is supported by the previous work of Sinyashin et al, that is, the thermal coupling reaction of N-isocyanurate-substituted azide to C 60 , the main product at 180uC is the open [5,6]-bridged monoadduct, but on the other hand the main product at 100uC is the closed [5,6]-bridged monoadduct (20).…”

“…During extrusion of N 2 , the steric effect of the leaving N 2 molecule prevents the addition of the nitrene substituent to the [6,6] ring junction attacked initially and forces the addition to an adjacent [5,6]-ring junction (19). It was suggested that the closed [5,6] monoadducts are intermediate products of dissociation without opening the fullerene framework (20). Thus, the closed [5,6] monoadducts may be formed by ultrasonic irradiation.…”

Materials for Flexible Organic Photovoltaic Cells: Conjugated Polymer MEH‐PPV/Fullerene Composites

“…Azahomofullerenes were prepared by method described in ref. (7,8) and poly(amino)fullerenes were prepared by the method described in ref. (9).…”

Synthesis and electrochemical properties of individual isomers of isocyanurate-substituted bis-organodiazadihomofullerenes

“…Azides 3-5 were prepared according to a procedure described earlier. [11][12][13] Elemental analysis was carried out on an Analizator CHN 3 instrument.…”