Synthesis and crystal structure of triphenyl[tris(tetrahydrofuran)]ytterbium, Ph3Yb(THF)3

Bochkarev, L. N.; Zheleznova, T. A.; Safronova, A. V.; Drozdov, M. S.; Zhil'tsov, S. F.; Zakharov, L. N.; Fukin, Georgy K.; Khorshev, S. Ya.

doi:10.1007/bf02495525

Cited by 14 publications

(13 citation statements)

References 18 publications

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“…Holmium trisalkyl complexes were previously isolated only with an N-chelating benzyl ligand, 9 although the corresponding trisphenyl complex is known. 37 The erbium trisneosilyl complex was reported by two groups but without structural characterization, 38,39 while ErPh 3 (THF) 3 was isolated and structurally characterized. 40 Both Ho and Er complexes gave pink crystals upon recrystallization.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

“…The corresponding Ho and Er trisbenzyl complexes were synthesized from the THF adducts MCl 3 (THF) 3.5 (eq ). Holmium trisalkyl complexes were previously isolated only with an N-chelating benzyl ligand, although the corresponding trisphenyl complex is known . The erbium trisneosilyl complex was reported by two groups but without structural characterization, , while ErPh 3 (THF) 3 was isolated and structurally characterized .…”

Section: Resultsmentioning

confidence: 99%

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Synthesis and Characterization of Paramagnetic Lanthanide Benzyl Complexes

et al. 2013

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The organometallic chemistry of paramagnetic lanthanides (Ln, from Ce to Yb) is far less developed compared to that of their diamagnetic counterparts (Sc, Y, La, and Lu). Lack of available starting materials and characterization methods are the major obstacles. Herein we report the synthesis and characterization of trisbenzyl complexes of neodymium, gadolinium, holmium, and erbium. In addition, we introduce a direct procedure for the synthesis of lanthanide benzyl and iodide complexes supported by a ferrocene diamide ligand starting from the corresponding oxides. All newly synthesized compounds were characterized by X-ray crystallography, 1 H NMR spectroscopy (except for gadolinium compounds, which were NMR silent), and elemental analysis.

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Section: ■ Results and Discussionmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Synthesis and Characterization of Paramagnetic Lanthanide Benzyl Complexes

et al. 2013

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“…As expected for the different oxidation state, this distance is ∼0.12 Å longer than the corresponding bond length in Yb(III)-C(aryl) compounds. [23][24][25] Similar distances are found in Yb(II) alkyls, which cover a range of 2.47 to 2.58 Å. 9 The Yb-I distance of 3.1148(5) Å may be compared with the Yb-I bond length in hexa-coordinate YbI 2 (thf) 4 4b which was determined to be 3.103(1) Å.…”

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confidence: 75%

Synthesis and First Structural Characterization of Lanthanide(II) Aryls: Observation of a Schlenk Equilibrium in Europium(II) and Ytterbium(II) Chemistry

2000

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“…[27] The long YbϪO (41) bond may be compared with the average YbϪO distance of 239.5 pm trans to the C 6 H 5 groups in facYbPh 3 (THF) 3 . [28] The trans influence of THF ligands in lanthanoid(III) chemistry has been noted previously. [29] Because of their very similar features, the solid-state structures of the compounds Eu(SAr*) 2 [4a·(THF) 0.5 ] and Yb(SAr*) 2 [4b·(C 6 H 6 ) 0.5 ] will be discussed together.…”

Section: Scheme 1 Syntheses Of Compounds 1ϫ5mentioning

confidence: 99%

σ-Donor versus η6-π-Arene Interactions in Monomeric Europium(II) and Ytterbium(II) Thiolates − An Experimental and Computational Study

Niemeyer

2001

Eur. J. Inorg. Chem.

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Keywords: Ab initio calculations / Lanthanides / π interactions / S ligands / YtterbiumThe base-free, hydrocarbon-soluble complexes M(SAr*) 2 (4a: M = Eu, orange; 4b: M = Yb, purple; Ar* = 2,6-Trip 2 C 6 H 3 ; Trip = 2,4,6-iPr 3 C 6 H 2 ) have been prepared by a protolysis reaction of the Grignard-analogous compound RLnI (R = 2-F 3 CC 6 H 4 ) with HSAr*. Compound 4b has been characterized by melting point, elemental analysis, 1 H, 13 C, and 171 Yb NMR, IR spectroscopy, UV/Vis spectrophotometry, mass spectrometry, and X-ray crystallography. Additionally, the purple Yb III complex YbI 2 (SAr*)(THF) 3 (3) and the yellow DME adduct Yb(SAr*) 2 (dme) 2 (5) have been synthesized and characterized by X-ray crystallography. The solid-state structures of 4a and 4b (as THF or benzene hemisolvates) show monomeric units with the metal atom bonded to two terminal

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Synthesis and crystal structure of triphenyl[tris(tetrahydrofuran)]ytterbium, Ph3Yb(THF)3

Cited by 14 publications

References 18 publications

Synthesis and Characterization of Paramagnetic Lanthanide Benzyl Complexes

Synthesis and Characterization of Paramagnetic Lanthanide Benzyl Complexes

Synthesis and First Structural Characterization of Lanthanide(II) Aryls: Observation of a Schlenk Equilibrium in Europium(II) and Ytterbium(II) Chemistry

σ-Donor versus η6-π-Arene Interactions in Monomeric Europium(II) and Ytterbium(II) Thiolates − An Experimental and Computational Study

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