Synthesis and crystal structure of a new inorganic – organic complex: (4‐ClC₇H₆NH₃)₉[Nd(P₆O₁₈)₂]·9H₂O

Abstract

(7), c = 20.695(6)Å, α = 102.04(3), β = 100.49(3), γ = 98.82(3)°, V = 5245 (4) 3 Å and Z = 2. The crystal structure has been solved and refined to R = 0.043 (Rw = 0.061) for 20420 observed reflections. The atomic arrangement of the title compound can be described as infinite layers built by complex of Neodyme [Nd(P 6 O 18 ) 2 ] and nine water molecules. The organic cations are located in the space delimited by the successive inorganic layers.