Synthesis and crystal structure of structurally different cadmium selenocyanate and thiocyanate coordination compounds containing 3‐chloropyridine as ligand
Abstract:Four compounds with the composition Cd(NCSe)2(3‐ClPy)4 (1), [Cd(NCSe)2(3‐ClPy)2] ⋅ 3‐ClPy (2), Cd(NCSe)2(3‐ClPy)2 (3) and Cd(NCSe)2(3‐ClPy) (4) with 3‐ClPy = 3‐chloropyridine were synthesized. In the structure of 1 discrete complexes are observed, whereas in 2 the Cd cations are linked by pairs of selenocyanato anions into chains and between the chains 3‐chloropyridine solvate molecules are embedded. In compound 3 each two Cd cations are linked by pairs of anionic ligands into dinuclear units, that are further… Show more
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